Magnesium Phosphides–Synthesis and Structure of [Mg(PHPh)2(tmeda)]

Evamarie Hey, Lutz M. Engelhardt, Colin L. Raston, Allan H. White

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

Application as PR 2⊕ transfer reagents is for‐seen for the new inorganic magnesium reagents [Mg(PHPh)2] and the crystalline, monomeric title compound 1. The latter was prepared in high yield by monometalation of PhPH2 with the versatile reagent nBusBuMg and addition of TMEDA. In 1 the MgP distances are equal but the MgPC angles are not. (Figure Presented.)

Original languageEnglish
Pages (from-to)81-82
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume26
Issue number1
DOIs
Publication statusPublished - Jan 1987
Externally publishedYes

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