Magnesium Phosphides–Synthesis and Structure of [Mg(PHPh)2(tmeda)]

Evamarie Hey; Lutz M. Engelhardt; Colin L. Raston; Allan H. White

doi:10.1002/anie.198700811

Magnesium Phosphides–Synthesis and Structure of [Mg(PHPh)₂(tmeda)]

Evamarie Hey, Lutz M. Engelhardt, Colin L. Raston, Allan H. White

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Abstract

Application as PR 2⊕ transfer reagents is for‐seen for the new inorganic magnesium reagents [Mg(PHPh)₂]_∞ and the crystalline, monomeric title compound 1. The latter was prepared in high yield by monometalation of PhPH₂ with the versatile reagent nBusBuMg and addition of TMEDA. In 1 the MgP distances are equal but the MgPC angles are not. (Figure Presented.)

Original language	English
Pages (from-to)	81-82
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	1
DOIs	https://doi.org/10.1002/anie.198700811
Publication status	Published - Jan 1987
Externally published	Yes

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abstract = "Application as PR 2⊕ transfer reagents is for‐seen for the new inorganic magnesium reagents [Mg(PHPh)2]∞ and the crystalline, monomeric title compound 1. The latter was prepared in high yield by monometalation of PhPH2 with the versatile reagent nBusBuMg and addition of TMEDA. In 1 the MgP distances are equal but the MgPC angles are not. (Figure Presented.)",

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AU - White, Allan H.

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AB - Application as PR 2⊕ transfer reagents is for‐seen for the new inorganic magnesium reagents [Mg(PHPh)2]∞ and the crystalline, monomeric title compound 1. The latter was prepared in high yield by monometalation of PhPH2 with the versatile reagent nBusBuMg and addition of TMEDA. In 1 the MgP distances are equal but the MgPC angles are not. (Figure Presented.)

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Magnesium Phosphides–Synthesis and Structure of [Mg(PHPh)₂(tmeda)]

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