Manipulating three-dimensional gel network entanglement by thin film shearing

Harshita Kumari; Steven Kline; Stuart Kennedy; Christopher Garvey; Colin Raston; Jerry Atwood; Jonathan Steed

doi:10.1039/c6cc00171h

Manipulating three-dimensional gel network entanglement by thin film shearing

Harshita Kumari, Steven Kline, Stuart Kennedy, Christopher Garvey, Colin Raston, Jerry Atwood, Jonathan Steed

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Vortex fluidic mediated shearing of supramolecular gels in thin films leads to complete disruption of fluorous bis-urea derived gels. Hydrocarbon analogues however, are only partially disrupted, which emphasizes the resistance of non-fluorous bis-urea gelators towards shear. The gel structures have been studied by combining the thin film shearing with small angle neutron scattering. This technique represents a novel approach to study the effects of external stimuli on self-assembled supramolecular gel networks.

Original language	English
Pages (from-to)	4513-4516
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	24
DOIs	https://doi.org/10.1039/c6cc00171h
Publication status	Published - 2016

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abstract = "Vortex fluidic mediated shearing of supramolecular gels in thin films leads to complete disruption of fluorous bis-urea derived gels. Hydrocarbon analogues however, are only partially disrupted, which emphasizes the resistance of non-fluorous bis-urea gelators towards shear. The gel structures have been studied by combining the thin film shearing with small angle neutron scattering. This technique represents a novel approach to study the effects of external stimuli on self-assembled supramolecular gel networks.",

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AU - Kline, Steven

AU - Kennedy, Stuart

AU - Garvey, Christopher

AU - Raston, Colin

AU - Atwood, Jerry

AU - Steed, Jonathan

PY - 2016

Y1 - 2016

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AB - Vortex fluidic mediated shearing of supramolecular gels in thin films leads to complete disruption of fluorous bis-urea derived gels. Hydrocarbon analogues however, are only partially disrupted, which emphasizes the resistance of non-fluorous bis-urea gelators towards shear. The gel structures have been studied by combining the thin film shearing with small angle neutron scattering. This technique represents a novel approach to study the effects of external stimuli on self-assembled supramolecular gel networks.

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SP - 4513

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JO - Chemical Communications

JF - Chemical Communications

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Manipulating three-dimensional gel network entanglement by thin film shearing

Abstract

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