Mapping out the diversity of interplay of O-alkylated calix[4]arenes

Adam Martin; Alexandre Sobolev; Colin Raston

doi:10.1039/c003053h

Mapping out the diversity of interplay of O-alkylated calix[4]arenes

Adam Martin, Alexandre Sobolev, Colin Raston

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

O-Alkylated calix[4]arenes with varying chain lengths, corresponding to C_nH_2n+1 where n = 12, 14 or 16, compounds 1-3 respectively, show that the arrangement of the molecules in the solid state has a profound dependence on n, with n = 12 and n = 16 resulting in an interdigitated bilayer arrangement, and n = 14 resulting in a head-to-head bilayer structure. Preliminary data collected also suggest that n = 12 is the lower limit for efficient packing, below which the packing is dominated by the calix[4]arene moiety.

Original language	English
Pages (from-to)	2666-2668
Number of pages	3
Journal	CrystEngComm
Volume	12
Issue number	10
DOIs	https://doi.org/10.1039/c003053h
Publication status	Published - Oct 2010

Access to Document

10.1039/c003053h

Cite this

@article{a0137d02f34c4fddb47e16f168ce2fb7,

title = "Mapping out the diversity of interplay of O-alkylated calix[4]arenes",

abstract = "O-Alkylated calix[4]arenes with varying chain lengths, corresponding to CnH2n+1 where n = 12, 14 or 16, compounds 1-3 respectively, show that the arrangement of the molecules in the solid state has a profound dependence on n, with n = 12 and n = 16 resulting in an interdigitated bilayer arrangement, and n = 14 resulting in a head-to-head bilayer structure. Preliminary data collected also suggest that n = 12 is the lower limit for efficient packing, below which the packing is dominated by the calix[4]arene moiety.",

author = "Adam Martin and Alexandre Sobolev and Colin Raston",

year = "2010",

month = oct,

doi = "10.1039/c003053h",

language = "English",

volume = "12",

pages = "2666--2668",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - Mapping out the diversity of interplay of O-alkylated calix[4]arenes

AU - Martin, Adam

AU - Sobolev, Alexandre

AU - Raston, Colin

PY - 2010/10

Y1 - 2010/10

N2 - O-Alkylated calix[4]arenes with varying chain lengths, corresponding to CnH2n+1 where n = 12, 14 or 16, compounds 1-3 respectively, show that the arrangement of the molecules in the solid state has a profound dependence on n, with n = 12 and n = 16 resulting in an interdigitated bilayer arrangement, and n = 14 resulting in a head-to-head bilayer structure. Preliminary data collected also suggest that n = 12 is the lower limit for efficient packing, below which the packing is dominated by the calix[4]arene moiety.

AB - O-Alkylated calix[4]arenes with varying chain lengths, corresponding to CnH2n+1 where n = 12, 14 or 16, compounds 1-3 respectively, show that the arrangement of the molecules in the solid state has a profound dependence on n, with n = 12 and n = 16 resulting in an interdigitated bilayer arrangement, and n = 14 resulting in a head-to-head bilayer structure. Preliminary data collected also suggest that n = 12 is the lower limit for efficient packing, below which the packing is dominated by the calix[4]arene moiety.

UR - http://www.scopus.com/inward/record.url?scp=77957694692&partnerID=8YFLogxK

U2 - 10.1039/c003053h

DO - 10.1039/c003053h

M3 - Article

SN - 1466-8033

VL - 12

SP - 2666

EP - 2668

JO - CrystEngComm

JF - CrystEngComm

IS - 10

ER -

Mapping out the diversity of interplay of O-alkylated calix[4]arenes

Abstract

Access to Document

Other files and links

Fingerprint

Cite this