TY - JOUR
T1 - Modern Ni and Pd–Ni Catalysts Supported on Sn–Al Binary Oxide for Oxy-Steam Reforming of Methanol
AU - Mierczynski, Pawel
AU - Mierczynska, Agnieszka
AU - Ciesielski, Radoslaw
AU - Maniukiewicz, Waldemar
AU - Rogowski, Jacek
AU - Maniecki, Tomasz P.
AU - Dubkov, Sergey
AU - Sysa, Artem
AU - Gromov, Dmitry
AU - Szynkowska, Malgorzata I.
AU - Vasilev, Krasimir
PY - 2018/9
Y1 - 2018/9
N2 - Monometallic Ni and bimetallic Pd–Ni catalysts supported on mono-SnO2 and SnO2–Al2O3 binary oxide are prepared using a wet impregnation and subsequent impregnation method. The catalysts are tested in oxy-steam reforming of methanol (OSRM) and characterized. The activity measurements show that palladium-promoted nickel catalysts supported on SnO2–Al2O3 exhibit high activity, selectivity towards hydrogen formation, and stability. The effect of Pd on reducibility, surface acidity, and morphology of the Ni supported catalyst, as well as its catalytic properties in OSRM, are discussed in detail.
AB - Monometallic Ni and bimetallic Pd–Ni catalysts supported on mono-SnO2 and SnO2–Al2O3 binary oxide are prepared using a wet impregnation and subsequent impregnation method. The catalysts are tested in oxy-steam reforming of methanol (OSRM) and characterized. The activity measurements show that palladium-promoted nickel catalysts supported on SnO2–Al2O3 exhibit high activity, selectivity towards hydrogen formation, and stability. The effect of Pd on reducibility, surface acidity, and morphology of the Ni supported catalyst, as well as its catalytic properties in OSRM, are discussed in detail.
KW - binary oxides
KW - hydrogen production
KW - palladium
KW - Pd-Ni catalysts
KW - supported catalysts
UR - http://www.scopus.com/inward/record.url?scp=85054057139&partnerID=8YFLogxK
U2 - 10.1002/ente.201700840
DO - 10.1002/ente.201700840
M3 - Article
AN - SCOPUS:85054057139
SN - 2194-4288
VL - 6
SP - 1687
EP - 1699
JO - Energy Technology
JF - Energy Technology
IS - 9
ER -