Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures

Hayden B Gearing; Tilo Söhnel; Paul Young; Lynn Lisboa; L James Wright; James D Crowley; Christian G Hartinger

doi:10.1039/d4cc03613a

Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)₄RuCl₂]²⁺ and [Pd(μ-L)₄Pt]⁴⁺ cage architectures

Hayden B Gearing
, Tilo Söhnel
, Paul Young
, Lynn Lisboa
, L James Wright
, James D Crowley
, Christian G Hartinger

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complementary properties of the guest to the host in terms of charge, size and H bonding properties.

Original language	English
Pages (from-to)	10950-10953
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	78
Early online date	30 Aug 2024
DOIs	https://doi.org/10.1039/d4cc03613a
Publication status	Published - 7 Oct 2024
Externally published	Yes

Keywords

Mixed-coordination geometry
Heterobimetallic cages
Bonding properties

Access to Document

10.1039/d4cc03613aLicence: In Copyright

Cite this

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title = "Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures",

abstract = "Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complementary properties of the guest to the host in terms of charge, size and H bonding properties.",

keywords = "Mixed-coordination geometry, Heterobimetallic cages, Bonding properties",

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AU - Gearing, Hayden B

AU - Söhnel, Tilo

AU - Young, Paul

AU - Lisboa, Lynn

AU - Wright, L James

AU - Crowley, James D

AU - Hartinger, Christian G

PY - 2024/10/7

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AB - Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complementary properties of the guest to the host in terms of charge, size and H bonding properties.

KW - Mixed-coordination geometry

KW - Heterobimetallic cages

KW - Bonding properties

UR - https://www.scopus.com/pages/publications/85204355882

U2 - 10.1039/d4cc03613a

DO - 10.1039/d4cc03613a

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AN - SCOPUS:85204355882

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