TY - JOUR
T1 - Monomeric selenolato- and tellurolato-aluminium(III) and -gallium(III) [Me3NM(ER)3] (E=Se, Te; R=alkyl, aryl), via trimethylamine alane/gallane cleavage of diorgano-dichalcogens
AU - Gardiner, Michael G.
AU - Raston, Colin L.
AU - Tolhurst, Vicki Anne
PY - 1995/7/21
Y1 - 1995/7/21
N2 - The reaction of diorgano-dichalcogens (ER)2 (E=Se or Te) with trimethylamine adducts of alane or gallane yields trimethylamine adducts of the tris(selenolato- or tellurolato-)metal (III) species [Me3NM(ER) 3] (M=Al, Ga; E=Se, Te; R=Et, Ph, CH2Ph); two of which have been structurally authenticated as four coordinate, monomeric species in the solid state.
AB - The reaction of diorgano-dichalcogens (ER)2 (E=Se or Te) with trimethylamine adducts of alane or gallane yields trimethylamine adducts of the tris(selenolato- or tellurolato-)metal (III) species [Me3NM(ER) 3] (M=Al, Ga; E=Se, Te; R=Et, Ph, CH2Ph); two of which have been structurally authenticated as four coordinate, monomeric species in the solid state.
UR - http://www.scopus.com/inward/record.url?scp=37049070529&partnerID=8YFLogxK
U2 - 10.1039/C39950001457
DO - 10.1039/C39950001457
M3 - Article
AN - SCOPUS:37049070529
SN - 0022-4936
SP - 1457
EP - 1458
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 14
ER -