TY - JOUR
T1 - N-functionalized amino-aluminium and -boron complexes
T2 - Intramolecular aromatic nitrogen-assisted formation of aminoboranes
AU - Engelhardt, Lutz M.
AU - Jacobsen, Geraldine E.
AU - Junk, Peter C.
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1990/1/1
Y1 - 1990/1/1
N2 - Reaction of 6-methyl-2-bis(trimethylsilyl)pyridine or 8-bis(trimethylsilyl) aminoquinoline with BCl3 in hexane results in facile elimination of ClSiMe3 affording an aminodichloroborane, (2) or (5a), then a novel aminobis(dichloroborane), (3) or (6); compounds (3) and (5b), prepared from a lithium reagent and AlCl3, have been structurally authenticated using X-ray diffraction data.
AB - Reaction of 6-methyl-2-bis(trimethylsilyl)pyridine or 8-bis(trimethylsilyl) aminoquinoline with BCl3 in hexane results in facile elimination of ClSiMe3 affording an aminodichloroborane, (2) or (5a), then a novel aminobis(dichloroborane), (3) or (6); compounds (3) and (5b), prepared from a lithium reagent and AlCl3, have been structurally authenticated using X-ray diffraction data.
UR - http://www.scopus.com/inward/record.url?scp=0002564964&partnerID=8YFLogxK
U2 - 10.1039/C39900000089
DO - 10.1039/C39900000089
M3 - Article
AN - SCOPUS:0002564964
SP - 89
EP - 91
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 1
ER -