N-functionalized amino-aluminium and -boron complexes: Intramolecular aromatic nitrogen-assisted formation of aminoboranes

Lutz M. Engelhardt; Geraldine E. Jacobsen; Peter C. Junk; Colin L. Raston; Allan H. White

doi:10.1039/C39900000089

N-functionalized amino-aluminium and -boron complexes: Intramolecular aromatic nitrogen-assisted formation of aminoboranes

Lutz M. Engelhardt, Geraldine E. Jacobsen, Peter C. Junk, Colin L. Raston, Allan H. White

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Reaction of 6-methyl-2-bis(trimethylsilyl)pyridine or 8-bis(trimethylsilyl) aminoquinoline with BCl₃ in hexane results in facile elimination of ClSiMe₃ affording an aminodichloroborane, (2) or (5a), then a novel aminobis(dichloroborane), (3) or (6); compounds (3) and (5b), prepared from a lithium reagent and AlCl₃, have been structurally authenticated using X-ray diffraction data.

Original language	English
Pages (from-to)	89-91
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39900000089
Publication status	Published - 1 Jan 1990
Externally published	Yes

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title = "N-functionalized amino-aluminium and -boron complexes: Intramolecular aromatic nitrogen-assisted formation of aminoboranes",

abstract = "Reaction of 6-methyl-2-bis(trimethylsilyl)pyridine or 8-bis(trimethylsilyl) aminoquinoline with BCl3 in hexane results in facile elimination of ClSiMe3 affording an aminodichloroborane, (2) or (5a), then a novel aminobis(dichloroborane), (3) or (6); compounds (3) and (5b), prepared from a lithium reagent and AlCl3, have been structurally authenticated using X-ray diffraction data.",

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year = "1990",

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doi = "10.1039/C39900000089",

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N-functionalized amino-aluminium and -boron complexes : Intramolecular aromatic nitrogen-assisted formation of aminoboranes. / Engelhardt, Lutz M.; Jacobsen, Geraldine E.; Junk, Peter C.; Raston, Colin L.; White, Allan H.

In: Journal of the Chemical Society, Chemical Communications, No. 1, 01.01.1990, p. 89-91.

Research output: Contribution to journal › Article › peer-review

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AU - Raston, Colin L.

AU - White, Allan H.

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