N-functionalized amino-aluminium and -boron complexes: Intramolecular aromatic nitrogen-assisted formation of aminoboranes

Lutz M. Engelhardt, Geraldine E. Jacobsen, Peter C. Junk, Colin L. Raston, Allan H. White

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

Reaction of 6-methyl-2-bis(trimethylsilyl)pyridine or 8-bis(trimethylsilyl) aminoquinoline with BCl3 in hexane results in facile elimination of ClSiMe3 affording an aminodichloroborane, (2) or (5a), then a novel aminobis(dichloroborane), (3) or (6); compounds (3) and (5b), prepared from a lithium reagent and AlCl3, have been structurally authenticated using X-ray diffraction data.
Original languageEnglish
Pages (from-to)89-91
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number1
DOIs
Publication statusPublished - 1 Jan 1990
Externally publishedYes

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