N,N′-di-tert-butylethylenediamine-ClnH 3-nAlNMe3 derivatives: Alane-rich [(H2Al) 2{μ-N(But)CH2}2] and stable, intramolecular secondary amine alane complexes [ClnH 2-NAl{N(H)(But)CH2CH2NBu t], n=0,1

Jerry L. Atwood; Stacey M. Lawrence; Colin L. Raston

doi:10.1039/C39940000073

N,N′-di-tert-butylethylenediamine-Cl_nH _3-nAlNMe₃ derivatives: Alane-rich [(H₂Al) ₂{μ-N(Bu^t)CH₂}₂] and stable, intramolecular secondary amine alane complexes [Cl_nH _2-NAl{N(H)(Bu^t)CH₂CH₂NBu ^t], n=0,1

Jerry L. Atwood, Stacey M. Lawrence, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

42 Citations (Scopus)

Abstract

Treatment of N,N′-di-tert-butylethylenediamine with two equivalents of H₃AlNMe₃ in diethyl ether affords a novel alane-rich amido species [(H₂Al)₂{μ-N(Bu^t)CH ₂}₂] 1, whereas with one equivalent a stable, intramolecularly coordinated secondary amine adduct of aluminium dihydride results, [H₂Al{N(H)(Bu^t)CH₂CH ₂NBu^t] 2; the monochloro analogue [Cl(H)Al{N(H)(Bu ^t)CH₂CH₂NBu^t] 3 is accessible using ClH₂AlNMe₃, as a mixture of diastereoisomers in solution.

Original language	English
Pages (from-to)	73-74
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39940000073
Publication status	Published - 7 Jan 1994
Externally published	Yes

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Atwood, J. L., Lawrence, S. M., & Raston, C. L. (1994). N,N′-di-tert-butylethylenediamine-Cl_nH _3-nAlNMe₃ derivatives: Alane-rich [(H₂Al) ₂{μ-N(Bu^t)CH₂}₂] and stable, intramolecular secondary amine alane complexes [Cl_nH _2-NAl{N(H)(Bu^t)CH₂CH₂NBu ^t], n=0,1 Journal of the Chemical Society, Chemical Communications, (1), 73-74. https://doi.org/10.1039/C39940000073

Atwood, Jerry L. ; Lawrence, Stacey M. ; Raston, Colin L. / N,N′-di-tert-butylethylenediamine-Cl_nH _3-nAlNMe₃ derivatives : Alane-rich [(H₂Al) ₂{μ-N(Bu^t)CH₂}₂] and stable, intramolecular secondary amine alane complexes [Cl_nH _2-NAl{N(H)(Bu^t)CH₂CH₂NBu ^t], n=0,1 In: Journal of the Chemical Society, Chemical Communications. 1994 ; No. 1. pp. 73-74.

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title = "N,N′-di-tert-butylethylenediamine-ClnH 3-nAlNMe3 derivatives: Alane-rich [(H2Al) 2{μ-N(But)CH2}2] and stable, intramolecular secondary amine alane complexes [ClnH 2-NAl{N(H)(But)CH2CH2NBu t], n=0,1 ",

abstract = "Treatment of N,N′-di-tert-butylethylenediamine with two equivalents of H3AlNMe3 in diethyl ether affords a novel alane-rich amido species [(H2Al)2{μ-N(But)CH 2}2] 1, whereas with one equivalent a stable, intramolecularly coordinated secondary amine adduct of aluminium dihydride results, [H2Al{N(H)(But)CH2CH 2NBut] 2; the monochloro analogue [Cl(H)Al{N(H)(Bu t)CH2CH2NBut] 3 is accessible using ClH2AlNMe3, as a mixture of diastereoisomers in solution.",

author = "Atwood, {Jerry L.} and Lawrence, {Stacey M.} and Raston, {Colin L.}",

year = "1994",

month = jan,

day = "7",

doi = "10.1039/C39940000073",

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Atwood, JL, Lawrence, SM & Raston, CL 1994, 'N,N′-di-tert-butylethylenediamine-Cl_nH _3-nAlNMe₃ derivatives: Alane-rich [(H₂Al) ₂{μ-N(Bu^t)CH₂}₂] and stable, intramolecular secondary amine alane complexes [Cl_nH _2-NAl{N(H)(Bu^t)CH₂CH₂NBu ^t], n=0,1 ', Journal of the Chemical Society, Chemical Communications, no. 1, pp. 73-74. https://doi.org/10.1039/C39940000073

N,N′-di-tert-butylethylenediamine-Cl_nH _3-nAlNMe₃ derivatives: Alane-rich [(H₂Al) ₂{μ-N(Bu^t)CH₂}₂] and stable, intramolecular secondary amine alane complexes [Cl_nH _2-NAl{N(H)(Bu^t)CH₂CH₂NBu ^t], n=0,1 . / Atwood, Jerry L.; Lawrence, Stacey M.; Raston, Colin L.
In: Journal of the Chemical Society, Chemical Communications, No. 1, 07.01.1994, p. 73-74.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - N,N′-di-tert-butylethylenediamine-ClnH 3-nAlNMe3 derivatives

T2 - Alane-rich [(H2Al) 2{μ-N(But)CH2}2] and stable, intramolecular secondary amine alane complexes [ClnH 2-NAl{N(H)(But)CH2CH2NBu t], n=0,1

AU - Atwood, Jerry L.

AU - Lawrence, Stacey M.

AU - Raston, Colin L.

PY - 1994/1/7

Y1 - 1994/1/7

N2 - Treatment of N,N′-di-tert-butylethylenediamine with two equivalents of H3AlNMe3 in diethyl ether affords a novel alane-rich amido species [(H2Al)2{μ-N(But)CH 2}2] 1, whereas with one equivalent a stable, intramolecularly coordinated secondary amine adduct of aluminium dihydride results, [H2Al{N(H)(But)CH2CH 2NBut] 2; the monochloro analogue [Cl(H)Al{N(H)(Bu t)CH2CH2NBut] 3 is accessible using ClH2AlNMe3, as a mixture of diastereoisomers in solution.

AB - Treatment of N,N′-di-tert-butylethylenediamine with two equivalents of H3AlNMe3 in diethyl ether affords a novel alane-rich amido species [(H2Al)2{μ-N(But)CH 2}2] 1, whereas with one equivalent a stable, intramolecularly coordinated secondary amine adduct of aluminium dihydride results, [H2Al{N(H)(But)CH2CH 2NBut] 2; the monochloro analogue [Cl(H)Al{N(H)(Bu t)CH2CH2NBut] 3 is accessible using ClH2AlNMe3, as a mixture of diastereoisomers in solution.

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U2 - 10.1039/C39940000073

DO - 10.1039/C39940000073

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SN - 0022-4936

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

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ER -

N,N′-di-tert-butylethylenediamine-Cl_nH _3-nAlNMe₃ derivatives: Alane-rich [(H₂Al) ₂{μ-N(Bu^t)CH₂}₂] and stable, intramolecular secondary amine alane complexes [Cl_nH _2-NAl{N(H)(Bu^t)CH₂CH₂NBu ^t], n=0,1

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