Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

Mohamed Makha; Alexandre N. Sobolev; Colin L. Raston

doi:10.1039/b513543e

Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

Mohamed Makha, Alexandre N. Sobolev, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Reaction of equimolar amounts of sodium para-sulfonato-calix[4]arene, tetraphenylphosphonium chloride and ytterbium chloride in water results in the formation of a mineral clay-like structure, where the hydrophobic tetraphenylphosphonium cations interpose a bilayer arrangement based on a 2D coordination polymer of (calix[4]arene)^5-/Na⁺/Yb ³⁺.

Original language	English
Pages (from-to)	57-59
Number of pages	3
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/b513543e
Publication status	Published - 6 Apr 2006
Externally published	Yes

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abstract = "Reaction of equimolar amounts of sodium para-sulfonato-calix[4]arene, tetraphenylphosphonium chloride and ytterbium chloride in water results in the formation of a mineral clay-like structure, where the hydrophobic tetraphenylphosphonium cations interpose a bilayer arrangement based on a 2D coordination polymer of (calix[4]arene)5-/Na+/Yb 3+.",

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AB - Reaction of equimolar amounts of sodium para-sulfonato-calix[4]arene, tetraphenylphosphonium chloride and ytterbium chloride in water results in the formation of a mineral clay-like structure, where the hydrophobic tetraphenylphosphonium cations interpose a bilayer arrangement based on a 2D coordination polymer of (calix[4]arene)5-/Na+/Yb 3+.

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Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

Abstract

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