One-Pot Ester Synthesis from Allyl and Benzyl Halides and Alcohols by Palladium-Catalyzed Carbonylation

Sara Tommasi; Serena Perrone; Francesca Rosato; Antonia Salomone; Luigino Troisi

doi:10.1055/s-0031-1289659

One-Pot Ester Synthesis from Allyl and Benzyl Halides and Alcohols by Palladium-Catalyzed Carbonylation

Sara Tommasi, Serena Perrone, Francesca Rosato, Antonia Salomone, Luigino Troisi

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbonylation of allylic and benzylic halides is described. The methodology has been applied to primary, secondary, and tertiary alcohols as well as to phenol derivatives. The O-protection of some biologically relevant molecules is also reported.

Original language	English
Article number	Z97311SS
Pages (from-to)	423-430
Number of pages	8
Journal	SYNTHESIS-STUTTGART
Volume	44
Issue number	3
DOIs	https://doi.org/10.1055/s-0031-1289659
Publication status	Published - 2012

Keywords

alcohols
allyl halides
benzyl halides
esterification
Pd-catalysis

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10.1055/s-0031-1289659

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abstract = "A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbonylation of allylic and benzylic halides is described. The methodology has been applied to primary, secondary, and tertiary alcohols as well as to phenol derivatives. The O-protection of some biologically relevant molecules is also reported.",

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AU - Perrone, Serena

AU - Rosato, Francesca

AU - Salomone, Antonia

AU - Troisi, Luigino

PY - 2012

Y1 - 2012

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AB - A mild and efficient one-pot synthesis of esters based on the Pd-catalyzed alkoxy- and aryloxycarbonylation of allylic and benzylic halides is described. The methodology has been applied to primary, secondary, and tertiary alcohols as well as to phenol derivatives. The O-protection of some biologically relevant molecules is also reported.

KW - alcohols

KW - allyl halides

KW - benzyl halides

KW - esterification

KW - Pd-catalysis

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One-Pot Ester Synthesis from Allyl and Benzyl Halides and Alcohols by Palladium-Catalyzed Carbonylation

Abstract

Keywords

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