TY - JOUR
T1 - Optimization of the power conversion efficiency in high bandgap pyridopyridinedithiophene-based conjugated polymers for organic photovoltaics by the random terpolymer approach
AU - Gedefaw, Desta
AU - Sharma, Anirudh
AU - Pan, Xun
AU - Bjuggren, Jonas
AU - Kroon, Renee
AU - Gregoriou, Vasilis
AU - Chochos, Christos
AU - Andersson, Mats R.
PY - 2017/6
Y1 - 2017/6
N2 -
We report that the organic photovoltaic (OPV) performance of wide band gap pyridopyridinedithiophene-based conjugated polymers can be significantly improved by employing the random terpolymer approach for the development of new pyridopyridinedithiophene-based conjugated polymers. This is demonstrated by the synthesis of the alternating copolymer (P1) consisting of 3,3′-difluoro-2,2′-bithiophene and pyridopyridinedithiophene and the random terpolymer (P2) containing pyridopyridinedithiophene 3,3′-difluoro-2,2′-bithiophene and thiophene. OPV devices fabricated by P1 and P2 in combination with PC
61
BM and PC
71
BM in an inverted device configuration exhibited power conversion efficiencies (PCEs) of 1.5% and 4.0%, respectively. We identified that the main reason for the enhanced performance of the OPV devices based on the P2 random copolymer was the improved morphology (miscibility) between P2 and PCBM as compared to P1. More specifically, atomic force microscopy (AFM) and scanning electron microscopy (SEM) studies revealed that the P1 based films showed rougher surface with clear crystallization/precipitation of the polymer chains even after the addition of chloronaphthalene (CN) to the chloroform processing solvent which significantly limited the short circuit current density (J
SC
), fill factor (FF) and overall performance of the prepared photovoltaic devices. On the other hand, P2 based films showed better miscibility with the acceptor particularly when processed using 5% CN containing chloroform solvent giving a respectable improvement in the PCE of the photovoltaic devices.
AB -
We report that the organic photovoltaic (OPV) performance of wide band gap pyridopyridinedithiophene-based conjugated polymers can be significantly improved by employing the random terpolymer approach for the development of new pyridopyridinedithiophene-based conjugated polymers. This is demonstrated by the synthesis of the alternating copolymer (P1) consisting of 3,3′-difluoro-2,2′-bithiophene and pyridopyridinedithiophene and the random terpolymer (P2) containing pyridopyridinedithiophene 3,3′-difluoro-2,2′-bithiophene and thiophene. OPV devices fabricated by P1 and P2 in combination with PC
61
BM and PC
71
BM in an inverted device configuration exhibited power conversion efficiencies (PCEs) of 1.5% and 4.0%, respectively. We identified that the main reason for the enhanced performance of the OPV devices based on the P2 random copolymer was the improved morphology (miscibility) between P2 and PCBM as compared to P1. More specifically, atomic force microscopy (AFM) and scanning electron microscopy (SEM) studies revealed that the P1 based films showed rougher surface with clear crystallization/precipitation of the polymer chains even after the addition of chloronaphthalene (CN) to the chloroform processing solvent which significantly limited the short circuit current density (J
SC
), fill factor (FF) and overall performance of the prepared photovoltaic devices. On the other hand, P2 based films showed better miscibility with the acceptor particularly when processed using 5% CN containing chloroform solvent giving a respectable improvement in the PCE of the photovoltaic devices.
KW - Photovoltaic
KW - Power conversion efficiency
KW - Pyridopyridinedithiophene
KW - Terpolymer
UR - http://doi.org/10.1016/j.eurpolymj.2017.03.044
UR - http://www.scopus.com/inward/record.url?scp=85016447034&partnerID=8YFLogxK
U2 - 10.1016/j.eurpolymj.2017.03.044
DO - 10.1016/j.eurpolymj.2017.03.044
M3 - Article
SN - 0014-3057
VL - 91
SP - 92
EP - 99
JO - European Polymer Journal
JF - European Polymer Journal
IS - June 2017
ER -