Paulscherrerite from the Number 2 Workings, Mount Painter Inlier, Northern Flinders Ranges, South Australia: "Dehydrated schoepite" is a mineral after all

Joel Brugger, Nicolas Meisser, Barbara Etschmann, Stefan Ansermet, Allan Pring

    Research output: Contribution to journalArticlepeer-review

    22 Citations (Scopus)

    Abstract

    Paulscherrerite, UO2(OH)2, occurs as an abundant dehydration product of metaschoepite at the Number 2 Workings at Radium Ridge, Northern Flinders Ranges, South Australia. The mineral name honors the contribution of Swiss physicist Paul Scherrer (1890-1969) to mineralogy and nuclear physics. Individual paulscherrerite crystals are tabular, reaching a maximum of 500 nm in length. Paulscherrerite has a canary yellow color and displays no fluorescence under UV light. Chemically, paulscherrerite is a pure uranyl hydroxide/hydrate, containing only traces of other metals (<1 wt% in total). Bulk (mg) samples always contain admixtures of metaschoepite (purest samples have ∼80 wt% paulscherrerite). A thermogravimetric analysis corrected for the presence of metaschoepite contamination leads to the empirical formula UO31.02H2O, and the simplified structural formula UO2(OH)2. Powder diffraction shows that the crystal structure of paulscherrerite is closely related to that of synthetic orthorhombic α-UO2(OH)2. However, splitting of some X-ray diffraction lines suggests a monoclinic symmetry for type paulscherrerite, with a = 4.288(2), b = 10.270(6), c = 6.885(5) Å, β = 90.39(4)°, V = 303.2(2) Å3, Z = 4, and possible space groups P2, P2 1, P2/m, or P21/m. Paulscherrerite-like material was synthesized using various methods, including heating metaschoepite in water at 150 °C and slow hydration of UO3(am) in air; material synthesized using hydrothermal techniques displayed peak splitting indicative of monoclinic symmetry. Paulscherrerite has been reported under the name "dehydrated schoepite" as an early weathering product of uraninite/pitchblende in several deposits, such as Shinkolobwe, Zaire; Nopal I deposit, Mexico; and the granitic pegmatites of New Hampshire, U.S.A.

    Original languageEnglish
    Pages (from-to)229-240
    Number of pages12
    JournalAmerican Mineralogist
    Volume96
    Issue number2-3
    DOIs
    Publication statusPublished - Feb 2011

    Keywords

    • New mineral
    • Northern Flinders Ranges
    • Number 2 Workings
    • Paulscherrerite
    • Powder diffraction
    • Radium ridge
    • South Australia
    • Uranyl hydroxide "dehydrated schoepite,"

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