Perturbations in the infrared spectrum of monofluoroacetylene, and their relationship to intramolecular vibrational energy redistribution

J. K. Holland; W. D. Lawrance; I. M. Mills

doi:10.1016/0022-2852(92)90572-6

Perturbations in the infrared spectrum of monofluoroacetylene, and their relationship to intramolecular vibrational energy redistribution

J. K. Holland, W. D. Lawrance, I. M. Mills

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Several high-order vibration-rotation perturbations in the high-resolution infrared spectrum of monofluoroacetylene, HCCF, are assigned and analyzed in detail. They result in avoided crossings in the rotational structure of several bands, and precise values for the effective high-order terms in the Hamiltonian have been determined. The significance of these results for intramolecular vibrational redistribution is discussed.

Original language	English
Pages (from-to)	369-377
Number of pages	9
Journal	JOURNAL OF MOLECULAR SPECTROSCOPY
Volume	151
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(92)90572-6
Publication status	Published - Feb 1992
Externally published	Yes

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title = "Perturbations in the infrared spectrum of monofluoroacetylene, and their relationship to intramolecular vibrational energy redistribution",

abstract = "Several high-order vibration-rotation perturbations in the high-resolution infrared spectrum of monofluoroacetylene, HCCF, are assigned and analyzed in detail. They result in avoided crossings in the rotational structure of several bands, and precise values for the effective high-order terms in the Hamiltonian have been determined. The significance of these results for intramolecular vibrational redistribution is discussed.",

author = "Holland, {J. K.} and Lawrance, {W. D.} and Mills, {I. M.}",

year = "1992",

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AU - Holland, J. K.

AU - Lawrance, W. D.

AU - Mills, I. M.

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Y1 - 1992/2

N2 - Several high-order vibration-rotation perturbations in the high-resolution infrared spectrum of monofluoroacetylene, HCCF, are assigned and analyzed in detail. They result in avoided crossings in the rotational structure of several bands, and precise values for the effective high-order terms in the Hamiltonian have been determined. The significance of these results for intramolecular vibrational redistribution is discussed.

AB - Several high-order vibration-rotation perturbations in the high-resolution infrared spectrum of monofluoroacetylene, HCCF, are assigned and analyzed in detail. They result in avoided crossings in the rotational structure of several bands, and precise values for the effective high-order terms in the Hamiltonian have been determined. The significance of these results for intramolecular vibrational redistribution is discussed.

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U2 - 10.1016/0022-2852(92)90572-6

DO - 10.1016/0022-2852(92)90572-6

M3 - Article

AN - SCOPUS:0009660721

VL - 151

SP - 369

EP - 377

JO - JOURNAL OF MOLECULAR SPECTROSCOPY

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ER -

Perturbations in the infrared spectrum of monofluoroacetylene, and their relationship to intramolecular vibrational energy redistribution

Abstract

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