Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Irene Ling; Harshita Kumari; Marzieh Mirzamani; Alexandre N. Sobolev; Christopher J. Garvey; Jerry L. Atwood; Colin L. Raston

doi:10.1039/c8cc05650a

Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Irene Ling, Harshita Kumari, Marzieh Mirzamani, Alexandre N. Sobolev, Christopher J. Garvey, Jerry L. Atwood, Colin L. Raston

Flinders Institute for Nanoscale Science and Technology

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

Original language	English
Pages (from-to)	10824-10827
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	77
DOIs	https://doi.org/10.1039/c8cc05650a
Publication status	Published - 14 Aug 2018

Keywords

icosahedra
dipicolinate
yttrium

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AU - Ling, Irene

AU - Kumari, Harshita

AU - Mirzamani, Marzieh

AU - Sobolev, Alexandre N.

AU - Garvey, Christopher J.

AU - Atwood, Jerry L.

AU - Raston, Colin L.

PY - 2018/8/14

Y1 - 2018/8/14

N2 - We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

AB - We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

KW - icosahedra

KW - dipicolinate

KW - yttrium

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DO - 10.1039/c8cc05650a

M3 - Article

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JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

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Keywords

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