Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Irene Ling, Harshita Kumari, Marzieh Mirzamani, Alexandre N. Sobolev, Christopher J. Garvey, Jerry L. Atwood, Colin L. Raston

    Research output: Contribution to journalArticlepeer-review

    3 Citations (Scopus)

    Abstract

    We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

    Original languageEnglish
    Pages (from-to)10824-10827
    Number of pages4
    JournalChemical Communications
    Volume54
    Issue number77
    DOIs
    Publication statusPublished - 14 Aug 2018

    Keywords

    • icosahedra
    • dipicolinate
    • yttrium

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