Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Irene Ling; Harshita Kumari; Marzieh Mirzamani; Alexandre N. Sobolev; Christopher J. Garvey; Jerry L. Atwood; Colin L. Raston

doi:10.1039/c8cc05650a

Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Irene Ling
, Harshita Kumari
, Marzieh Mirzamani
, Alexandre N. Sobolev
, Christopher J. Garvey
, Jerry L. Atwood
, Colin L. Raston

Flinders Institute for Nanoscale Science and Technology

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

Original language	English
Pages (from-to)	10824-10827
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	77
DOIs	https://doi.org/10.1039/c8cc05650a
Publication status	Published - 14 Aug 2018

Keywords

icosahedra
dipicolinate
yttrium

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10.1039/c8cc05650aLicence: In Copyright

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abstract = "We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.",

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AU - Ling, Irene

AU - Kumari, Harshita

AU - Mirzamani, Marzieh

AU - Sobolev, Alexandre N.

AU - Garvey, Christopher J.

AU - Atwood, Jerry L.

AU - Raston, Colin L.

PY - 2018/8/14

Y1 - 2018/8/14

N2 - We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

AB - We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(iii) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

KW - icosahedra

KW - dipicolinate

KW - yttrium

UR - https://www.scopus.com/pages/publications/85053891964

U2 - 10.1039/c8cc05650a

DO - 10.1039/c8cc05650a

M3 - Article

AN - SCOPUS:85053891964

SN - 1359-7345

VL - 54

SP - 10824

EP - 10827

JO - Chemical Communications

JF - Chemical Communications

IS - 77

ER -

Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Abstract

Keywords

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