Plastic lasers: Semiconducting polymers as a new class of solid-state laser materials

We demonstrate optically pumped lasing in submicron thick films, neat and undiluted, of photoluminescent conjugated polymers. Lasing is evidenced by a dramatic collapse of the emission line width (to as little as 7 nm) at very low pump energy thresholds (∼10 μJ/cm²). Laser action is found in over a dozen different conjugated polymers representing a variety of molecular structures, including poly(p-phenylenevinylene), poly(p-phenylene) and polyfluorene derivatives; lasing wavelengths in these materials span the visible spectrum. The short gain lengths in these conjugated polymers are attributed to the high density of chromophores, the large density of states associated with the interband (π-π*) transition in quasi-one-dimensional systems, and the Stokes shift which minimizes self-absorption and enhances stimulated emission in the absence of excited state absorption. The observation of lasing in this new class of solid-state laser materials is explained in terms of simple planar waveguiding structures which allow the distance traveled by emitted photons to readily exceed the short intrinsic gain lengths. The dependence of the threshold and the gain narrowed line width on the solvent from which the film is spin cast suggests that chain packing can be used to control lasing in some of these materials. The prospects for producing electrically pumped solid state polymer diode lasers using this class of materials are discussed in the context of the low-threshold gain narrowing in submicron films.