Polymer networks of imine-crosslinked metal-organic cages: tuneable viscoelasticity and iodine adsorption

Matthew L. Schneider; Jonathan A. Campbell; Ashley D. Slattery; Witold M. Bloch

doi:10.1039/d2cc04969d

Polymer networks of imine-crosslinked metal-organic cages: tuneable viscoelasticity and iodine adsorption

Matthew L. Schneider, Jonathan A. Campbell, Ashley D. Slattery, Witold M. Bloch

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The solution-state structure of an amine-functionalised Cu₂₄L₂₄ cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.

Original language	English
Pages (from-to)	12122-12125
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	86
Early online date	6 Oct 2022
DOIs	https://doi.org/10.1039/d2cc04969d
Publication status	Published - 7 Nov 2022

Keywords

Polymers
Polymer networks
metal-organic cages

Access to Document

10.1039/d2cc04969dLicence: In Copyright

Cite this

@article{765e911853124888ad26903632fca79b,

title = "Polymer networks of imine-crosslinked metal-organic cages: tuneable viscoelasticity and iodine adsorption",

abstract = "The solution-state structure of an amine-functionalised Cu24L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.",

keywords = "Polymers, Polymer networks, metal-organic cages",

author = "Schneider, {Matthew L.} and Campbell, {Jonathan A.} and Slattery, {Ashley D.} and Bloch, {Witold M.}",

year = "2022",

month = nov,

day = "7",

doi = "10.1039/d2cc04969d",

language = "English",

volume = "58",

pages = "12122--12125",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "ChemComm Communication",

number = "86",

}

TY - JOUR

T1 - Polymer networks of imine-crosslinked metal-organic cages

T2 - tuneable viscoelasticity and iodine adsorption

AU - Schneider, Matthew L.

AU - Campbell, Jonathan A.

AU - Slattery, Ashley D.

AU - Bloch, Witold M.

PY - 2022/11/7

Y1 - 2022/11/7

N2 - The solution-state structure of an amine-functionalised Cu24L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.

AB - The solution-state structure of an amine-functionalised Cu24L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.

KW - Polymers

KW - Polymer networks

KW - metal-organic cages

UR - http://www.scopus.com/inward/record.url?scp=85140830637&partnerID=8YFLogxK

UR - http://purl.org/au-research/grants/ARC/DE190100327

U2 - 10.1039/d2cc04969d

DO - 10.1039/d2cc04969d

M3 - Article

C2 - 36226547

AN - SCOPUS:85140830637

SN - 1359-7345

VL - 58

SP - 12122

EP - 12125

JO - Chemical Communications

JF - Chemical Communications

IS - 86

ER -

Polymer networks of imine-crosslinked metal-organic cages: tuneable viscoelasticity and iodine adsorption

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this