Polymer networks of imine-crosslinked metal-organic cages: tuneable viscoelasticity and iodine adsorption

Matthew L. Schneider, Jonathan A. Campbell, Ashley D. Slattery, Witold M. Bloch

Research output: Contribution to journalArticlepeer-review

Abstract

The solution-state structure of an amine-functionalised Cu24L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.

Original languageEnglish
Pages (from-to)12122-12125
Number of pages4
JournalChemical Communications
Volume58
Issue number86
Early online date6 Oct 2022
DOIs
Publication statusPublished - 7 Nov 2022

Keywords

  • Polymers
  • Polymer networks
  • metal-organic cages

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