Polymer supported alkali metal naphthalenides: Application in the generation of lithium and sodium reagents

Tania R. Van Den Ancker; Graeme R. Hanson; Fu Chin Lee; Colin L. Raston

doi:10.1039/a606181h

Polymer supported alkali metal naphthalenides: Application in the generation of lithium and sodium reagents

Tania R. Van Den Ancker, Graeme R. Hanson, Fu Chin Lee, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Polymer supported lithium and sodium naphthalenide complexes are prepared from the reaction of THF solutions of lithium and sodium biphenylide with polystyrene bearing -CH₂SiMe₂(1-C₁₀H₇) groups, generating highly coloured paramagnetic material, which afford lithium and sodium reagents in high yield when treated with organic halides, nitriles and phosphates.

Original language	English
Pages (from-to)	125-126
Number of pages	2
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/a606181h
Publication status	Published - 1 Jan 1997
Externally published	Yes

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title = "Polymer supported alkali metal naphthalenides: Application in the generation of lithium and sodium reagents",

abstract = "Polymer supported lithium and sodium naphthalenide complexes are prepared from the reaction of THF solutions of lithium and sodium biphenylide with polystyrene bearing -CH2SiMe2(1-C10H7) groups, generating highly coloured paramagnetic material, which afford lithium and sodium reagents in high yield when treated with organic halides, nitriles and phosphates.",

author = "{Van Den Ancker}, {Tania R.} and Hanson, {Graeme R.} and Lee, {Fu Chin} and Raston, {Colin L.}",

year = "1997",

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AU - Hanson, Graeme R.

AU - Lee, Fu Chin

AU - Raston, Colin L.

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AB - Polymer supported lithium and sodium naphthalenide complexes are prepared from the reaction of THF solutions of lithium and sodium biphenylide with polystyrene bearing -CH2SiMe2(1-C10H7) groups, generating highly coloured paramagnetic material, which afford lithium and sodium reagents in high yield when treated with organic halides, nitriles and phosphates.

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