Land use change is a major factor influencing catchment hydrology and groundwater resources. In South Africa, the management of scarce water resources is a big concern. The study area, the upper Berg catchment, Western Cape, South Africa, contains strategic water resources. The catchment has undergone many changes in recent years, not least of all the construction of a dam on the upper reach. To reduce water loss due to evapotranspiration, non-native hill slope vegetation upstream of the Berg River Dam was cut down. It was hypothesised that recharge has been increased due to this change in vegetation. The objectives of this study were to determine land use changes in upper Berg catchment using multi-temporal Landsat images from 1984, 1992, 2002, and 2008, and to predict the impact of these land use changes on groundwater recharge. For the simulation of groundwater recharge the distributed hydrological model WetSpa was used. Forest plantations lost 72% (18.8 km2) of their areal extent between 1984 and 2008, due to deforestation as part of a plan to implement the ecological Reserve as required by national water policy; the area of barren land increased by 15.7 km2 in the same period. The high increase in precipitation, especially in the period of 2005-2009, combined with the change in land use in the study area resulted in a highly increased (278%) predicted mean groundwater recharge. Simulated groundwater recharge shows strong spatial differences for each evaluated year. The effect of the rapid clearing of non-native hill slope vegetation upstream of the Berg River Dam for the land use scenario of 2008 was tested to check if clearing is an important factor in the increase of groundwater recharge. Hence, we simulated the whole time-series from 1984-2004 (21 years) with the land use map from 2008 instead of the land use maps for 1984, 1992 and 2002. A systematic increase of about 8% per year for the 21-year period, due to the change in land use from the different years to that of 2008, is predicted, which confirms that the clearing of the non-native hill slope vegetation is of considerable importance for the increase in groundwater recharge.