Primary and secondary directing interactions of aquated lanthanide(III) ions with p-sulfonated calix[n]arene

Irene Ling; Colin L. Raston

doi:10.1016/j.ccr.2017.11.004

Primary and secondary directing interactions of aquated lanthanide(III) ions with p-sulfonated calix[n]arene

Irene Ling, Colin L. Raston

Research output: Contribution to journal › Review article › peer-review

13 Citations (Scopus)

Abstract

This review reports on the solid-state structural analysis of primary and secondary coordination interactions between aquated lanthanide(III) ions and p-sulfonatocalix[n]arenes. These different interactions control the nature of the overall packing motif of the two components in the solid-state, with a diverse range of structures accessible. Structures with higher complexity can form in ternary systems, incorporating either or both endo- and exo-calixarene cavity guest molecules.

Original language	English
Pages (from-to)	80-105
Number of pages	26
Journal	Coordination Chemistry Reviews
Volume	375
DOIs	https://doi.org/10.1016/j.ccr.2017.11.004
Publication status	Published - 15 Nov 2018

Keywords

Lanthanides
Metal coordination
Self-assembly
Sulfonatocalix[n]arenes
Supramolecular chemistry

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abstract = "This review reports on the solid-state structural analysis of primary and secondary coordination interactions between aquated lanthanide(III) ions and p-sulfonatocalix[n]arenes. These different interactions control the nature of the overall packing motif of the two components in the solid-state, with a diverse range of structures accessible. Structures with higher complexity can form in ternary systems, incorporating either or both endo- and exo-calixarene cavity guest molecules.",

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AU - Ling, Irene

AU - Raston, Colin L.

PY - 2018/11/15

Y1 - 2018/11/15

N2 - This review reports on the solid-state structural analysis of primary and secondary coordination interactions between aquated lanthanide(III) ions and p-sulfonatocalix[n]arenes. These different interactions control the nature of the overall packing motif of the two components in the solid-state, with a diverse range of structures accessible. Structures with higher complexity can form in ternary systems, incorporating either or both endo- and exo-calixarene cavity guest molecules.

AB - This review reports on the solid-state structural analysis of primary and secondary coordination interactions between aquated lanthanide(III) ions and p-sulfonatocalix[n]arenes. These different interactions control the nature of the overall packing motif of the two components in the solid-state, with a diverse range of structures accessible. Structures with higher complexity can form in ternary systems, incorporating either or both endo- and exo-calixarene cavity guest molecules.

KW - Lanthanides

KW - Metal coordination

KW - Self-assembly

KW - Sulfonatocalix[n]arenes

KW - Supramolecular chemistry

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U2 - 10.1016/j.ccr.2017.11.004

DO - 10.1016/j.ccr.2017.11.004

M3 - Review article

AN - SCOPUS:85034607240

VL - 375

SP - 80

EP - 105

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

ER -

Primary and secondary directing interactions of aquated lanthanide(III) ions with p-sulfonated calix[n]arene

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Keywords

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