RAFT polymerization and thiol-ene modification of 2-vinyloxyethyl methacrylate: Towards functional branched polymers

Zhongfan Jia; Jinquan Liu; Thomas P. Davis; Volga Bulmus

doi:10.1016/j.polymer.2009.10.030

RAFT polymerization and thiol-ene modification of 2-vinyloxyethyl methacrylate: Towards functional branched polymers

Zhongfan Jia, Jinquan Liu, Thomas P. Davis, Volga Bulmus

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

A vinyl functional polymer, viz, poly(vinyloxyethyl methacrylate) (poly(VEMA) was synthesized by the RAFT polymerization of an asymmetric divinyl monomer, VEMA. This polymer, with pendant vinyloxyl groups, was subsequently reacted with three thiol compounds; 2-mercaptoethanol, cysteamine and 3-mercaptoproponic acid via the thiol-ene reactions. The resulting branched polymers contained hydroxyl, amino and carboxylic acid functionalities suitable for further reactions and conjugations.

Original language	English
Pages (from-to)	5928-5932
Number of pages	5
Journal	Polymer
Volume	50
Issue number	25
DOIs	https://doi.org/10.1016/j.polymer.2009.10.030
Publication status	Published - 27 Nov 2009
Externally published	Yes

Keywords

Branched polymer
RAFT polymerization
Thiol-ene click reaction

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abstract = "A vinyl functional polymer, viz, poly(vinyloxyethyl methacrylate) (poly(VEMA) was synthesized by the RAFT polymerization of an asymmetric divinyl monomer, VEMA. This polymer, with pendant vinyloxyl groups, was subsequently reacted with three thiol compounds; 2-mercaptoethanol, cysteamine and 3-mercaptoproponic acid via the thiol-ene reactions. The resulting branched polymers contained hydroxyl, amino and carboxylic acid functionalities suitable for further reactions and conjugations.",

keywords = "Branched polymer, RAFT polymerization, Thiol-ene click reaction",

author = "Zhongfan Jia and Jinquan Liu and Davis, {Thomas P.} and Volga Bulmus",

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AU - Jia, Zhongfan

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AU - Davis, Thomas P.

AU - Bulmus, Volga

PY - 2009/11/27

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AB - A vinyl functional polymer, viz, poly(vinyloxyethyl methacrylate) (poly(VEMA) was synthesized by the RAFT polymerization of an asymmetric divinyl monomer, VEMA. This polymer, with pendant vinyloxyl groups, was subsequently reacted with three thiol compounds; 2-mercaptoethanol, cysteamine and 3-mercaptoproponic acid via the thiol-ene reactions. The resulting branched polymers contained hydroxyl, amino and carboxylic acid functionalities suitable for further reactions and conjugations.

KW - Branched polymer

KW - RAFT polymerization

KW - Thiol-ene click reaction

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RAFT polymerization and thiol-ene modification of 2-vinyloxyethyl methacrylate: Towards functional branched polymers

Abstract

Keywords

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