TY - JOUR
T1 - Reduction of Bu2tC=O by H3MNMe3 (M = Al or Ga)
T2 - Product association via bridging alkyloxides (M = Al, Ga) and hydrides (M = Al)
AU - Koutsantonis, George A.
AU - Lee, Fu Chin
AU - Raston, Colin L.
PY - 1995
Y1 - 1995
N2 - Treatment of di-t-butyl ketone with excess H3MNMe3, M = Al or Ga, yields dimeric [H2M{훍-OC(H)But2}]2 which for M = A1 association prevails, in the solid via two symmetrical bridging hydrides between single aluminium centers from different dimers such that the metal centers are either four or five coordinate, as distorted tetrahedra or square pyramids.
AB - Treatment of di-t-butyl ketone with excess H3MNMe3, M = Al or Ga, yields dimeric [H2M{훍-OC(H)But2}]2 which for M = A1 association prevails, in the solid via two symmetrical bridging hydrides between single aluminium centers from different dimers such that the metal centers are either four or five coordinate, as distorted tetrahedra or square pyramids.
UR - http://www.scopus.com/inward/record.url?scp=0002202093&partnerID=8YFLogxK
U2 - 10.1080/13583149512331338235
DO - 10.1080/13583149512331338235
M3 - Article
AN - SCOPUS:0002202093
SN - 1024-1221
VL - 1
SP - 21
EP - 28
JO - Main Group Chemistry
JF - Main Group Chemistry
IS - 1
ER -