Reduction of Bu2tC=O by H3MNMe3 (M = Al or Ga): Product association via bridging alkyloxides (M = Al, Ga) and hydrides (M = Al)

George A. Koutsantonis; Fu Chin Lee; Colin L. Raston

doi:10.1080/13583149512331338235

Reduction of Bu₂^tC=O by H₃MNMe₃ (M = Al or Ga): Product association via bridging alkyloxides (M = Al, Ga) and hydrides (M = Al)

George A. Koutsantonis
, Fu Chin Lee
, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Treatment of di-t-butyl ketone with excess H₃MNMe₃, M = Al or Ga, yields dimeric [H₂M{훍-OC(H)Bu^t₂}]₂ which for M = A1 association prevails, in the solid via two symmetrical bridging hydrides between single aluminium centers from different dimers such that the metal centers are either four or five coordinate, as distorted tetrahedra or square pyramids.

Original language	English
Pages (from-to)	21-28
Number of pages	8
Journal	Main Group Chemistry
Volume	1
Issue number	1
DOIs	https://doi.org/10.1080/13583149512331338235
Publication status	Published - 1995
Externally published	Yes

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title = "Reduction of Bu2tC=O by H3MNMe3 (M = Al or Ga): Product association via bridging alkyloxides (M = Al, Ga) and hydrides (M = Al)",

abstract = "Treatment of di-t-butyl ketone with excess H3MNMe3, M = Al or Ga, yields dimeric [H2M\{훍-OC(H)But2\}]2 which for M = A1 association prevails, in the solid via two symmetrical bridging hydrides between single aluminium centers from different dimers such that the metal centers are either four or five coordinate, as distorted tetrahedra or square pyramids.",

author = "Koutsantonis, \{George A.\} and Lee, \{Fu Chin\} and Raston, \{Colin L.\}",

year = "1995",

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journal = "Main Group Chemistry",

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T1 - Reduction of Bu2tC=O by H3MNMe3 (M = Al or Ga)

T2 - Product association via bridging alkyloxides (M = Al, Ga) and hydrides (M = Al)

AU - Koutsantonis, George A.

AU - Lee, Fu Chin

AU - Raston, Colin L.

PY - 1995

Y1 - 1995

N2 - Treatment of di-t-butyl ketone with excess H3MNMe3, M = Al or Ga, yields dimeric [H2M{훍-OC(H)But2}]2 which for M = A1 association prevails, in the solid via two symmetrical bridging hydrides between single aluminium centers from different dimers such that the metal centers are either four or five coordinate, as distorted tetrahedra or square pyramids.

AB - Treatment of di-t-butyl ketone with excess H3MNMe3, M = Al or Ga, yields dimeric [H2M{훍-OC(H)But2}]2 which for M = A1 association prevails, in the solid via two symmetrical bridging hydrides between single aluminium centers from different dimers such that the metal centers are either four or five coordinate, as distorted tetrahedra or square pyramids.

UR - https://www.scopus.com/pages/publications/0002202093

U2 - 10.1080/13583149512331338235

DO - 10.1080/13583149512331338235

M3 - Article

AN - SCOPUS:0002202093

SN - 1024-1221

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EP - 28

JO - Main Group Chemistry

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IS - 1

ER -

Reduction of Bu₂^tC=O by H₃MNMe₃ (M = Al or Ga): Product association via bridging alkyloxides (M = Al, Ga) and hydrides (M = Al)

Abstract

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