Scandium(III) coordination polymers containing capsules based on two p-sulfonatocalix[4]arenes

Helen R. Webb; Michaele J. Hardie; Colin L. Raston

doi:10.1002/1521-3765(20010817)7:16<3616::AID-CHEM3616>3.0.CO;2-V

Scandium(III) coordination polymers containing capsules based on two p-sulfonatocalix[4]arenes

Helen R. Webb
, Michaele J. Hardie
, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

Reactions of sodium p-sulfonatocalix[4]arene and scandium(III) tristriflate in the presence, and absence, of [18]crown-6 give the crystalline complexes [Sc₂(μ-OH)₂(H₂O)₁₀] {Na₄(H₂O)₈-[calix[4]arene(SO₃) ₄]₂} · 13H₂O and {[Sc₂(μ-OH)₂(H₂O)₈] [Sc(H₂O)₄]₂[calix[4]-arene(SO₃) ₄-H⁺]₂([18]crown-6)} · 16 H₂O. Both complexes involve novel coordination polymers with calixarene units linked through sodium or scandium centers and also feature capsule assemblies through to the head-to-head association of calixarenes. A linear array of capsules associated with an infinite chain of aquo-bridged sodium ions, and an aquated hydroxy-bridged scandium(III) dimer, [Sc₂(μ-OH)₂(H₂O)₁₀] ⁴⁺, are found in the absence of the crown ether. In the presence of [18]crown-6 both hydrated scandium monomers and dimers bridge between calixarenes in a two-dimensional coordination network. The crown ethers reside in cavities created by two calixarenes from adjacent polymeric sheets via a variety of supramolecular interactions(hydrogen-bonding, shape complementarity), and effectively add a third dimension to the network. The extended structure of both of these polymers is highly porous, and resembles a bilayer.

Original language	English
Pages (from-to)	3616-3620
Number of pages	5
Journal	Chemistry - A European Journal
Volume	7
Issue number	16
DOIs	https://doi.org/10.1002/1521-3765(20010817)7:16<3616::AID-CHEM3616>3.0.CO;2-V
Publication status	Published - 17 Aug 2001
Externally published	Yes

Keywords

Calixarenes
Coordination polymers
Host-guest systems
Scandium

Access to Document

10.1002/1521-3765(20010817)7:16<3616::AID-CHEM3616>3.0.CO;2-VLicence: In Copyright

Cite this

@article{5b6cf3f9b9b343e3988e685ef7bd1334,

title = "Scandium(III) coordination polymers containing capsules based on two p-sulfonatocalix[4]arenes",

abstract = "Reactions of sodium p-sulfonatocalix[4]arene and scandium(III) tristriflate in the presence, and absence, of [18]crown-6 give the crystalline complexes [Sc2(μ-OH)2(H2O)10] \{Na4(H2O)8-[calix[4]arene(SO3) 4]2\} · 13H2O and \{[Sc2(μ-OH)2(H2O)8] [Sc(H2O)4]2[calix[4]-arene(SO3) 4-H+]2([18]crown-6)\} · 16 H2O. Both complexes involve novel coordination polymers with calixarene units linked through sodium or scandium centers and also feature capsule assemblies through to the head-to-head association of calixarenes. A linear array of capsules associated with an infinite chain of aquo-bridged sodium ions, and an aquated hydroxy-bridged scandium(III) dimer, [Sc2(μ-OH)2(H2O)10] 4+, are found in the absence of the crown ether. In the presence of [18]crown-6 both hydrated scandium monomers and dimers bridge between calixarenes in a two-dimensional coordination network. The crown ethers reside in cavities created by two calixarenes from adjacent polymeric sheets via a variety of supramolecular interactions(hydrogen-bonding, shape complementarity), and effectively add a third dimension to the network. The extended structure of both of these polymers is highly porous, and resembles a bilayer.",

keywords = "Calixarenes, Coordination polymers, Host-guest systems, Scandium",

author = "Webb, \{Helen R.\} and Hardie, \{Michaele J.\} and Raston, \{Colin L.\}",

year = "2001",

month = aug,

day = "17",

doi = "10.1002/1521-3765(20010817)7:16<3616::AID-CHEM3616>3.0.CO;2-V",

language = "English",

volume = "7",

pages = "3616--3620",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley \& Sons, Inc",

number = "16",

}

TY - JOUR

T1 - Scandium(III) coordination polymers containing capsules based on two p-sulfonatocalix[4]arenes

AU - Webb, Helen R.

AU - Hardie, Michaele J.

AU - Raston, Colin L.

PY - 2001/8/17

Y1 - 2001/8/17

N2 - Reactions of sodium p-sulfonatocalix[4]arene and scandium(III) tristriflate in the presence, and absence, of [18]crown-6 give the crystalline complexes [Sc2(μ-OH)2(H2O)10] {Na4(H2O)8-[calix[4]arene(SO3) 4]2} · 13H2O and {[Sc2(μ-OH)2(H2O)8] [Sc(H2O)4]2[calix[4]-arene(SO3) 4-H+]2([18]crown-6)} · 16 H2O. Both complexes involve novel coordination polymers with calixarene units linked through sodium or scandium centers and also feature capsule assemblies through to the head-to-head association of calixarenes. A linear array of capsules associated with an infinite chain of aquo-bridged sodium ions, and an aquated hydroxy-bridged scandium(III) dimer, [Sc2(μ-OH)2(H2O)10] 4+, are found in the absence of the crown ether. In the presence of [18]crown-6 both hydrated scandium monomers and dimers bridge between calixarenes in a two-dimensional coordination network. The crown ethers reside in cavities created by two calixarenes from adjacent polymeric sheets via a variety of supramolecular interactions(hydrogen-bonding, shape complementarity), and effectively add a third dimension to the network. The extended structure of both of these polymers is highly porous, and resembles a bilayer.

AB - Reactions of sodium p-sulfonatocalix[4]arene and scandium(III) tristriflate in the presence, and absence, of [18]crown-6 give the crystalline complexes [Sc2(μ-OH)2(H2O)10] {Na4(H2O)8-[calix[4]arene(SO3) 4]2} · 13H2O and {[Sc2(μ-OH)2(H2O)8] [Sc(H2O)4]2[calix[4]-arene(SO3) 4-H+]2([18]crown-6)} · 16 H2O. Both complexes involve novel coordination polymers with calixarene units linked through sodium or scandium centers and also feature capsule assemblies through to the head-to-head association of calixarenes. A linear array of capsules associated with an infinite chain of aquo-bridged sodium ions, and an aquated hydroxy-bridged scandium(III) dimer, [Sc2(μ-OH)2(H2O)10] 4+, are found in the absence of the crown ether. In the presence of [18]crown-6 both hydrated scandium monomers and dimers bridge between calixarenes in a two-dimensional coordination network. The crown ethers reside in cavities created by two calixarenes from adjacent polymeric sheets via a variety of supramolecular interactions(hydrogen-bonding, shape complementarity), and effectively add a third dimension to the network. The extended structure of both of these polymers is highly porous, and resembles a bilayer.

KW - Calixarenes

KW - Coordination polymers

KW - Host-guest systems

KW - Scandium

UR - https://www.scopus.com/pages/publications/0035902868

U2 - 10.1002/1521-3765(20010817)7:16<3616::AID-CHEM3616>3.0.CO;2-V

DO - 10.1002/1521-3765(20010817)7:16<3616::AID-CHEM3616>3.0.CO;2-V

M3 - Article

C2 - 11560333

AN - SCOPUS:0035902868

SN - 0947-6539

VL - 7

SP - 3616

EP - 3620

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 16

ER -

Scandium(III) coordination polymers containing capsules based on two p-sulfonatocalix[4]arenes

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this