Self-assembling polymeric mixed donor (O/N) N-ethylmorpholine adducts of alane (AlH3)

Philip C. Andrews; Colin L. Raston; Brian W. Skelton; Allan H. White

doi:10.1039/a607916d

Self-assembling polymeric mixed donor (O/N) N-ethylmorpholine adducts of alane (AlH₃)

Philip C. Andrews, Colin L. Raston, Brian W. Skelton, Allan H. White

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The 2:3 and 1:2 stoichiometric reactions of N-ethyl morpholine with the Et₂O adduct of AlH₃, prepared from LiAlH₄ and H₂SO₄ in Et₂O at -80°C, afford alane-rich hydride-bridged polymers exhibiting a range of bonding modes of Lewis bases to AlH₃ including unprecedented mono Al⋯H hydride bridging.

Original language	English
Pages (from-to)	245-246
Number of pages	2
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/a607916d
Publication status	Published - 1 Jan 1997
Externally published	Yes

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title = "Self-assembling polymeric mixed donor (O/N) N-ethylmorpholine adducts of alane (AlH3)",

abstract = "The 2:3 and 1:2 stoichiometric reactions of N-ethyl morpholine with the Et2O adduct of AlH3, prepared from LiAlH4 and H2SO4 in Et2O at -80°C, afford alane-rich hydride-bridged polymers exhibiting a range of bonding modes of Lewis bases to AlH3 including unprecedented mono Al⋯H hydride bridging.",

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AU - Andrews, Philip C.

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - White, Allan H.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The 2:3 and 1:2 stoichiometric reactions of N-ethyl morpholine with the Et2O adduct of AlH3, prepared from LiAlH4 and H2SO4 in Et2O at -80°C, afford alane-rich hydride-bridged polymers exhibiting a range of bonding modes of Lewis bases to AlH3 including unprecedented mono Al⋯H hydride bridging.

AB - The 2:3 and 1:2 stoichiometric reactions of N-ethyl morpholine with the Et2O adduct of AlH3, prepared from LiAlH4 and H2SO4 in Et2O at -80°C, afford alane-rich hydride-bridged polymers exhibiting a range of bonding modes of Lewis bases to AlH3 including unprecedented mono Al⋯H hydride bridging.

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Self-assembling polymeric mixed donor (O/N) N-ethylmorpholine adducts of alane (AlH₃)

Abstract

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