Self-sorting of porous Cu4L2L'2metal-organic cages composed of isomerisable ligands

Adrian W. Markwell-Heys; Matthew L. Schneider; Jenica Marie L. Madridejos; Gregory F. Metha; Witold M. Bloch

doi:10.1039/d0cc08076d

Self-sorting of porous Cu₄L₂L'₂metal-organic cages composed of isomerisable ligands

Adrian W. Markwell-Heys, Matthew L. Schneider, Jenica Marie L. Madridejos, Gregory F. Metha, Witold M. Bloch

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

We report the self-sorting of a dynamic combinatorial library (DCL) of metal-organic cages composed of a rotationally isomerisable ligand. Convergence of the DCL occurs upon crystallisation and leads to low-symmetry Cu₄L₂L'₂cages that display differing porosities based on their overall shape and ligand configuration.

Original language	English
Pages (from-to)	2915-2918
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	23
Early online date	16 Feb 2021
DOIs	https://doi.org/10.1039/d0cc08076d
Publication status	Published - 21 Mar 2021
Externally published	Yes

Keywords

metal–organic cages
Cu4L2L′2
ligands

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abstract = "We report the self-sorting of a dynamic combinatorial library (DCL) of metal-organic cages composed of a rotationally isomerisable ligand. Convergence of the DCL occurs upon crystallisation and leads to low-symmetry Cu4L2L'2cages that display differing porosities based on their overall shape and ligand configuration.",

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AU - Schneider, Matthew L.

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AU - Metha, Gregory F.

AU - Bloch, Witold M.

PY - 2021/3/21

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KW - metal–organic cages

KW - Cu4L2L′2

KW - ligands

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Self-sorting of porous Cu₄L₂L'₂metal-organic cages composed of isomerisable ligands

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Keywords

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