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Shortest derivation of Time-Independent Perturbation Theory

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Abstract

We present a new derivation of Time-Independent Perturbation Theory (PT) that is shorter and more general than the usual ones presented in Quantum Mechanics (QM) texts. Expressing the task of PT in terms of Green's functions, the key to our approach is to write the bound-state equation for the perturbed wave function directly in terms of the unperturbed Green's function. Not only does this greatly simplify the derivation of PT expressions for energies and wave functions, but it does so without using the orthogonality or completeness properties of unperturbed Hamiltonian eigenstates, which form the basis of standard derivations of PT. As a result, our approach does not require the potentials to be energy independent as is required in standard derivations, nor does it require the inverse free Green's operator G_0^{-1}(E) to be a linear function of energy, as is the case in QM. Consequently, our approach is applicable not only to QM but also to various extensions of QM, including Quantum Field Theory. For students, our approach provides an easy-to-understand introduction to the use of Green's functions in QM while at the same time presenting a description of PT that is shorter and more fundamental than the standard ones currently advocated.
Original languageEnglish
Pages (from-to)652–658
Number of pages7
JournalAmerican Journal of Physics
Volume93
Issue number8
DOIs
Publication statusPublished - Aug 2025

Keywords

  • time-independent perturbation theory
  • Quantum mechanics
  • Green's functions
  • bound-state equation
  • perturbed wave function
  • Quantum field theory

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