Solid state supramolecular assemblies of charged supermolecules (Na[2.2.2]cryptate)+ and anionic carboranes with host cyclotriveratrylene

M. J. Hardie; C. L. Raston

doi:10.1039/b009581h

Solid state supramolecular assemblies of charged supermolecules (Na[2.2.2]cryptate)⁺ and anionic carboranes with host cyclotriveratrylene

M. J. Hardie, C. L. Raston

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

The complex {(Na[2.2.2]cryptate)[CTV][Co(C₂B₉H₁₁) ₂]}₂(MeCN) (CTV = cyclotriveratrylene) features (Na[2.2.2]cryptate)+∩CTV interplay as well as a closely packed chain of [Co(C₂B₉H₁₁)₂]^- counter-anions exhibiting dihydrogen bonding, and a similar cation-CTV assembly is found in (Na[2.2.2]cryptate)[CTV](CHCl₃)₃[CB₁₁H ₁₂].

Original language	English
Pages (from-to)	905-906
Number of pages	2
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/b009581h
Publication status	Published - 21 May 2001
Externally published	Yes

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title = "Solid state supramolecular assemblies of charged supermolecules (Na[2.2.2]cryptate)+ and anionic carboranes with host cyclotriveratrylene",

abstract = "The complex {(Na[2.2.2]cryptate)[CTV][Co(C2B9H11) 2]}2(MeCN) (CTV = cyclotriveratrylene) features (Na[2.2.2]cryptate)+∩CTV interplay as well as a closely packed chain of [Co(C2B9H11)2]- counter-anions exhibiting dihydrogen bonding, and a similar cation-CTV assembly is found in (Na[2.2.2]cryptate)[CTV](CHCl3)3[CB11H 12].",

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Solid state supramolecular assemblies of charged supermolecules (Na[2.2.2]cryptate)⁺ and anionic carboranes with host cyclotriveratrylene

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