Stereospecific synthesis of resorcin[4]arenes and pyrogallol[4]arenes in dynamic thin films

Lyzu Yasmin; Travis Coyle; Keith Stubbs; Colin Raston

doi:10.1039/c3cc45176c

Stereospecific synthesis of resorcin[4]arenes and pyrogallol[4]arenes in dynamic thin films

Lyzu Yasmin, Travis Coyle, Keith Stubbs, Colin Raston

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Acid catalysed condensation of resorcinol and pyrogallol with aromatic aldehydes using a microfluidic vortex fluidic device (VFD) under continuous flow conditions results in the selective formation of resorcin[4]arenes and pyrogallol[4]arenes as predominantly their C_4v isomers. Notably C_2v isomers and C_2h isomers can be also prepared with the latter being converted to the C_4v isomer when the VFD operates in confined mode.

Original language	English
Pages (from-to)	10932-10934
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	93
DOIs	https://doi.org/10.1039/c3cc45176c
Publication status	Published - 29 Oct 2013

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abstract = "Acid catalysed condensation of resorcinol and pyrogallol with aromatic aldehydes using a microfluidic vortex fluidic device (VFD) under continuous flow conditions results in the selective formation of resorcin[4]arenes and pyrogallol[4]arenes as predominantly their C4v isomers. Notably C2v isomers and C2h isomers can be also prepared with the latter being converted to the C4v isomer when the VFD operates in confined mode.",

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AU - Yasmin, Lyzu

AU - Coyle, Travis

AU - Stubbs, Keith

AU - Raston, Colin

PY - 2013/10/29

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N2 - Acid catalysed condensation of resorcinol and pyrogallol with aromatic aldehydes using a microfluidic vortex fluidic device (VFD) under continuous flow conditions results in the selective formation of resorcin[4]arenes and pyrogallol[4]arenes as predominantly their C4v isomers. Notably C2v isomers and C2h isomers can be also prepared with the latter being converted to the C4v isomer when the VFD operates in confined mode.

AB - Acid catalysed condensation of resorcinol and pyrogallol with aromatic aldehydes using a microfluidic vortex fluidic device (VFD) under continuous flow conditions results in the selective formation of resorcin[4]arenes and pyrogallol[4]arenes as predominantly their C4v isomers. Notably C2v isomers and C2h isomers can be also prepared with the latter being converted to the C4v isomer when the VFD operates in confined mode.

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U2 - 10.1039/c3cc45176c

DO - 10.1039/c3cc45176c

M3 - Article

SN - 1359-7345

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EP - 10934

JO - Chemical Communications

JF - Chemical Communications

IS - 93

ER -

Stereospecific synthesis of resorcin[4]arenes and pyrogallol[4]arenes in dynamic thin films

Abstract

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