Stereospecific synthisis of 2,3-dihydro-2-metallaphenalenes, meso-[M(η-C5H5)2R2][M = Zr, Hf; R2=(CHSiME3)2C10H6], via an unstable dilithium reagent, [R2(Li(tmeda))2](tmeda = tetramethyl-ethylenediamine), which is coverted the complex [CHSiMe2C(SiMe3)C10H6][Li(tmeda)]2 containing a silicon heterocycle dicarbanion
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Dive into the research topics of 'Stereospecific synthisis of 2,3-dihydro-2-metallaphenalenes, meso-[M(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>R<sub>2</sub>][M = Zr, Hf; R<sub>2</sub>=(CHSiME<sub>3</sub>)<sub>2</sub>C<sub>10</sub>H<sub>6</sub>], via an unstable dilithium reagent, [R<sub>2</sub>(Li(tmeda))<sub>2</sub>](tmeda = tetramethyl-ethylenediamine), which is coverted the complex [CHSiMe<sub>2</sub>C(SiMe<sub>3</sub>)C<sub>10</sub>H<sub>6</sub>][Li(tmeda)]<sub>2</sub> containing a silicon heterocycle dicarbanion'. Together they form a unique fingerprint.