Structural studies in the ruthenium-dithiocarbamate system. Part IV. Crystal structure of a trinuclear ruthenium(II) carbonyl dithiocarbamate chloride

Colin L. Raston, Allan H. White

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Abstract

The crystal structure of the title complex [Ru3(CS2·NEt2)4(CO) 3Cl2] has been determined by the heavy-atom method from X-ray diffractometer data and refined to R 0.068 for 1 407 reflections. Crystals are triclinic, space group P1, a = 13.964(5), b = 13.919(9), c = 11.073(5) Å, α = 102.09(4), β = 109.91(3), γ = 95.51(4)°, Z = 2. The complex is trinuclear with ruthenium(II) atoms linked by bridging sulphur and bi- and ter-dentate chlorine atoms.

Original languageEnglish
Pages (from-to)2422-2425
Number of pages4
JournalJournal of the Chemical Society, Dalton Transactions
Issue number22
DOIs
Publication statusPublished - 1975
Externally publishedYes

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