TY - JOUR
T1 - Structural studies of group 5B-halide-dithio-ligand complexes. Part 3. Crystal structure of polymeric (NN-diethyldithiocarbamato)di-iodobismuth(III)
AU - Raston, Colin L.
AU - Rowbottom, Graham L.
AU - White, Allan H.
PY - 1981
Y1 - 1981
N2 - The crystal structure of the title compound, [Bi(S2CNEt2)l2], has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least-squares procedures to a conventional residual of 0.045 for 1 537 'observed' reflections. Crystals are monoclinic, space group P21/c, with a = 10.673(3), b = 15.001(3), c = 8.149(2) Å, β = 90.86(2)°, and Z = 4. The structure comprises an infinite linear polymeric array, successive bismuth atoms being bridged by a pair of iodine atoms and a ligand sulphur atom.
AB - The crystal structure of the title compound, [Bi(S2CNEt2)l2], has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least-squares procedures to a conventional residual of 0.045 for 1 537 'observed' reflections. Crystals are monoclinic, space group P21/c, with a = 10.673(3), b = 15.001(3), c = 8.149(2) Å, β = 90.86(2)°, and Z = 4. The structure comprises an infinite linear polymeric array, successive bismuth atoms being bridged by a pair of iodine atoms and a ligand sulphur atom.
UR - http://www.scopus.com/inward/record.url?scp=37049108657&partnerID=8YFLogxK
U2 - 10.1039/DT9810001366
DO - 10.1039/DT9810001366
M3 - Article
AN - SCOPUS:37049108657
SP - 1366
EP - 1368
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
SN - 1470-479X
IS - 6
ER -