Abstract
The crystal structure of the title compound, [Bi(S2CNEt2)l2], has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least-squares procedures to a conventional residual of 0.045 for 1 537 'observed' reflections. Crystals are monoclinic, space group P21/c, with a = 10.673(3), b = 15.001(3), c = 8.149(2) Å, β = 90.86(2)°, and Z = 4. The structure comprises an infinite linear polymeric array, successive bismuth atoms being bridged by a pair of iodine atoms and a ligand sulphur atom.
| Original language | English |
|---|---|
| Pages (from-to) | 1366-1368 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Dalton Transactions |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 1981 |
| Externally published | Yes |
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Raston, C. L., Rowbottom, G. L., & White, A. H. (1981). Structural studies of group 5B-halide-dithio-ligand complexes. Part 3. Crystal structure of polymeric (NN-diethyldithiocarbamato)di-iodobismuth(III). Journal of the Chemical Society, Dalton Transactions, (6), 1366-1368. https://doi.org/10.1039/DT9810001366