Structural studies of group 5B-halide-dithio-ligand complexes. Part 3. Crystal structure of polymeric (NN-diethyldithiocarbamato)di-iodobismuth(III)

Colin L. Raston, Graham L. Rowbottom, Allan H. White

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Bi(S2CNEt2)l2], has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least-squares procedures to a conventional residual of 0.045 for 1 537 'observed' reflections. Crystals are monoclinic, space group P21/c, with a = 10.673(3), b = 15.001(3), c = 8.149(2) Å, β = 90.86(2)°, and Z = 4. The structure comprises an infinite linear polymeric array, successive bismuth atoms being bridged by a pair of iodine atoms and a ligand sulphur atom.

Original languageEnglish
Pages (from-to)1366-1368
Number of pages3
JournalJournal of the Chemical Society, Dalton Transactions
Issue number6
DOIs
Publication statusPublished - 1981
Externally publishedYes

Fingerprint Dive into the research topics of 'Structural studies of group 5B-halide-dithio-ligand complexes. Part 3. Crystal structure of polymeric (NN-diethyldithiocarbamato)di-iodobismuth(III)'. Together they form a unique fingerprint.

  • Cite this