Structural studies of group 5B-halide-dithio-ligand complexes. Part 6. Crystal structures of dichloro (NN-diethyldithiocarbamato) tris(pyridine)-bismuth(III)-pyridine (1/1) and its di-iodo-analogue

Colin L. Raston; Graham L. Rowbottom; Allan H. White

doi:10.1039/DT9810001379

Structural studies of group 5B-halide-dithio-ligand complexes. Part 6. Crystal structures of dichloro (NN-diethyldithiocarbamato) tris(pyridine)-bismuth(III)-pyridine (1/1) and its di-iodo-analogue

Colin L. Raston, Graham L. Rowbottom, Allan H. White

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

Recrystallization of [Bi(S₂CNEt₂)X₂], X = Cl, Br, or I, from pyridine solution has been shown to yield adducts Bi(S₂CNEt₂)X₂(py)₄. Single-crystal X-ray structure determinations have shown the three compounds to be isomorphous within a monoclinic unit cell (P2₁/c) with a ca. 13.7, b ca. 14.4, c ca. 16.0 Å, β ca. 93-101°, Z = 4, and to comprise [Bi(S₂CNEt₂)X₂(py)₃] molecules with a further pyridine solvate molecule in the lattice. The bismuth environment is pseudo-seven-co-ordinate, the pyridine ligands being rather loosely bound, and the stereochemistry pseudo-pentagonal bipyramidal, with axial halogen substituents (Bi-Cl,2.6₉; Bi-l, 3.0₆Å).

Original language	English
Pages (from-to)	1379-1382
Number of pages	4
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	6
DOIs	https://doi.org/10.1039/DT9810001379
Publication status	Published - 1981
Externally published	Yes

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Raston, C. L., Rowbottom, G. L., & White, A. H. (1981). Structural studies of group 5B-halide-dithio-ligand complexes. Part 6. Crystal structures of dichloro (NN-diethyldithiocarbamato) tris(pyridine)-bismuth(III)-pyridine (1/1) and its di-iodo-analogue. Journal of the Chemical Society, Dalton Transactions, (6), 1379-1382. https://doi.org/10.1039/DT9810001379

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title = "Structural studies of group 5B-halide-dithio-ligand complexes. Part 6. Crystal structures of dichloro (NN-diethyldithiocarbamato) tris(pyridine)-bismuth(III)-pyridine (1/1) and its di-iodo-analogue",

abstract = "Recrystallization of [Bi(S2CNEt2)X2], X = Cl, Br, or I, from pyridine solution has been shown to yield adducts Bi(S2CNEt2)X2(py)4. Single-crystal X-ray structure determinations have shown the three compounds to be isomorphous within a monoclinic unit cell (P21/c) with a ca. 13.7, b ca. 14.4, c ca. 16.0 {\AA}, β ca. 93-101°, Z = 4, and to comprise [Bi(S2CNEt2)X2(py)3] molecules with a further pyridine solvate molecule in the lattice. The bismuth environment is pseudo-seven-co-ordinate, the pyridine ligands being rather loosely bound, and the stereochemistry pseudo-pentagonal bipyramidal, with axial halogen substituents (Bi-Cl,2.69; Bi-l, 3.06{\AA}).",

author = "Raston, {Colin L.} and Rowbottom, {Graham L.} and White, {Allan H.}",

year = "1981",

doi = "10.1039/DT9810001379",

language = "English",

pages = "1379--1382",

journal = "Journal of the Chemical Society, Dalton Transactions",

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number = "6",

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Structural studies of group 5B-halide-dithio-ligand complexes. Part 6. Crystal structures of dichloro (NN-diethyldithiocarbamato) tris(pyridine)-bismuth(III)-pyridine (1/1) and its di-iodo-analogue. / Raston, Colin L.; Rowbottom, Graham L.; White, Allan H.

In: Journal of the Chemical Society, Dalton Transactions, No. 6, 1981, p. 1379-1382.

Research output: Contribution to journal › Article

TY - JOUR

T1 - Structural studies of group 5B-halide-dithio-ligand complexes. Part 6. Crystal structures of dichloro (NN-diethyldithiocarbamato) tris(pyridine)-bismuth(III)-pyridine (1/1) and its di-iodo-analogue

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N2 - Recrystallization of [Bi(S2CNEt2)X2], X = Cl, Br, or I, from pyridine solution has been shown to yield adducts Bi(S2CNEt2)X2(py)4. Single-crystal X-ray structure determinations have shown the three compounds to be isomorphous within a monoclinic unit cell (P21/c) with a ca. 13.7, b ca. 14.4, c ca. 16.0 Å, β ca. 93-101°, Z = 4, and to comprise [Bi(S2CNEt2)X2(py)3] molecules with a further pyridine solvate molecule in the lattice. The bismuth environment is pseudo-seven-co-ordinate, the pyridine ligands being rather loosely bound, and the stereochemistry pseudo-pentagonal bipyramidal, with axial halogen substituents (Bi-Cl,2.69; Bi-l, 3.06Å).

AB - Recrystallization of [Bi(S2CNEt2)X2], X = Cl, Br, or I, from pyridine solution has been shown to yield adducts Bi(S2CNEt2)X2(py)4. Single-crystal X-ray structure determinations have shown the three compounds to be isomorphous within a monoclinic unit cell (P21/c) with a ca. 13.7, b ca. 14.4, c ca. 16.0 Å, β ca. 93-101°, Z = 4, and to comprise [Bi(S2CNEt2)X2(py)3] molecules with a further pyridine solvate molecule in the lattice. The bismuth environment is pseudo-seven-co-ordinate, the pyridine ligands being rather loosely bound, and the stereochemistry pseudo-pentagonal bipyramidal, with axial halogen substituents (Bi-Cl,2.69; Bi-l, 3.06Å).

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