Structural studies of Group 5B-halide-dithio-ligand complexes. Part 8. Crystal structure of N′N′-diethylthiocarbamoylpyridinium pentachloropyridinebismuthate(III)

Colin L. Raston, Graham L. Rowbottom, Allan H. White

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15 Citations (Scopus)

Abstract

The crystal structure of the title compound, [C5H5NCSNEt2]2[BiCl 5(C5H5N)], has been determined by single-crystal X-ray diffraction methods at 295(1) K and refined by least-squares procedures to a conventional residual of 0.031 for 1 633 'observed' reflections. Crystals are orthorhombic, space group Pbcn, with a = 16.089(4), b = 14.852(4), c = 14.130(3) Å, and Z = 4. The anion lies on a crystallographic two-fold axis; Bi-N is 2.615(8) Å. The Bi-Cl distance trans to the Bi-N bond is shorter [2.637(3) Å] than the remainder [2.692(2), 2.700(3) Å]. The N-Bi-Cl (cis) angles are appreciably less than 90° [84.65(6), 84.91 (6°)].

Original languageEnglish
Pages (from-to)1389-1391
Number of pages3
JournalJournal of the Chemical Society, Dalton Transactions
Issue number6
DOIs
Publication statusPublished - 1981
Externally publishedYes

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