Structural tuning of quinoxaline-benzodithiophene copolymers via alkyl side chain manipulation: synthesis, characterization and photovoltaic properties

Marta Tessarolo, Desta Gedefaw, Margherita Bolognesi, Fabiola Liscio, Patrik Henriksson, Wenliu Zhuang, Silvia Milita, Michele Muccini, Ergang Wang, Mirko Seri, Mats R. Andersson

    Research output: Contribution to journalArticlepeer-review

    30 Citations (Scopus)

    Abstract

    We report here the synthesis and characterization of two novel semiconducting quinoxaline (FQ)-benzodithiophene (BDT) based copolymers, PFQBDT-TR1 and PFQBDT-T2R2, in which the BDT unit is substituted with either 2-octylthienyl (-TR1) or 2,3-dihexylthienyl (-T2R2), respectively, as side groups. The effect of the alkyl side chain(s), linked to the thienyl side groups, on the optical, electronic and morphological properties of the resulting polymers is investigated and correlated with the photovoltaic performance. Solution-processed BHJ solar cells, using these copolymers as electron donor materials and PC61BM (or PC71BM) as an electron acceptor counterpart, are prepared by a blade-coating technique under ambient conditions. As a result, power conversion efficiencies (PCEs) of ∼5.7% and ∼3.4% have been achieved for PFQBDT-TR1 and PFQBDT-T2R2 based devices, respectively, highlighting the crucial role of the alkyl portion of the π-conjugated side segment in the optoelectronic properties of this class of copolymers.

    Original languageEnglish
    Pages (from-to)11162-11170
    Number of pages9
    JournalJournal of Materials Chemistry A
    Volume2
    Issue number29
    DOIs
    Publication statusPublished - 2014

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