Sub-glass transition annealing enhances polymer solar cell performance,

Jonas Bergqvist, Camilla Lindqvist, Olof Backe, Zaifei Ma, Zheng Tang, Wolfgang Tress, Stefan Gustafsson, Ergang Wang, Eva Olsson, Mats R. Andersson, Olle Inganas, Christian Muller

    Research output: Contribution to journalArticlepeer-review

    49 Citations (Scopus)


    Thermal annealing of non-crystalline polymer:fullerene blends typically results in a drastic decrease in solar cell performance. In particular aggressive annealing above the glass transition temperature results in a detrimental coarsening of the blend nanostructure. We demonstrate that mild annealing below the glass transition temperature is a viable avenue to control the nanostructure of a non-crystalline thiophene-quinoxaline copolymer:fullerene blend. Direct imaging methods indicate that coarsening of the blend nanostructure can be avoided. However, a combination of absorption and luminescence spectroscopy reveals that local changes in the polymer conformation as well as limited fullerene aggregation are permitted to occur. As a result, we are able to optimise the solar cell performance evenly across different positions of the coated area, which is a necessary criterion for large-scale, high throughput production. This journal is

    Original languageEnglish
    Pages (from-to)6146-6152
    Number of pages7
    JournalJournal of Materials Chemistry A
    Issue number17
    Publication statusPublished - 7 May 2014


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