Sulfur-Limonene Polysulfide: A Material Synthesized Entirely from Industrial By-Products and Its Use in Removing Toxic Metals from Water and Soil

Michael Crockett; Austin Evans; Max Worthington; Ines Albuquerque; Ashley Slattery; Christopher Gibson; Jonathan Campbell; David Lewis; Goncalo Bernardes; Justin Chalker

doi:10.1002/anie.201508708

Sulfur-Limonene Polysulfide: A Material Synthesized Entirely from Industrial By-Products and Its Use in Removing Toxic Metals from Water and Soil

Michael Crockett, Austin Evans, Max Worthington, Ines Albuquerque, Ashley Slattery, Christopher Gibson, Jonathan Campbell, David Lewis, Goncalo Bernardes, Justin Chalker

Research output: Contribution to journal › Article › peer-review

288 Citations (Scopus)

Abstract

A polysulfide material was synthesized by the direct reaction of sulfur and d-limonene, by-products of the petroleum and citrus industries, respectively. The resulting material was processed into functional coatings or molded into solid devices for the removal of palladium and mercury salts from water and soil. The binding of mercury(II) to the sulfur-limonene polysulfide resulted in a color change. These properties motivate application in next-generation environmental remediation and mercury sensing.

Original language	English
Pages (from-to)	1714-1718
Number of pages	5
Journal	Angewandte Chemie-International Edition
Volume	55
Issue number	5
DOIs	https://doi.org/10.1002/anie.201508708
Publication status	Published - 26 Jan 2016

Keywords

limonene
polysulfide
sulfur
sustainable materials
waste valorization

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10.1002/anie.201508708

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Crockett, M., Evans, A., Worthington, M., Albuquerque, I., Slattery, A., Gibson, C., Campbell, J., Lewis, D., Bernardes, G., & Chalker, J. (2016). Sulfur-Limonene Polysulfide: A Material Synthesized Entirely from Industrial By-Products and Its Use in Removing Toxic Metals from Water and Soil. Angewandte Chemie-International Edition, 55(5), 1714-1718. https://doi.org/10.1002/anie.201508708

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abstract = "A polysulfide material was synthesized by the direct reaction of sulfur and d-limonene, by-products of the petroleum and citrus industries, respectively. The resulting material was processed into functional coatings or molded into solid devices for the removal of palladium and mercury salts from water and soil. The binding of mercury(II) to the sulfur-limonene polysulfide resulted in a color change. These properties motivate application in next-generation environmental remediation and mercury sensing.",

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Crockett, M, Evans, A, Worthington, M, Albuquerque, I, Slattery, A, Gibson, C , Campbell, J , Lewis, D, Bernardes, G & Chalker, J 2016, 'Sulfur-Limonene Polysulfide: A Material Synthesized Entirely from Industrial By-Products and Its Use in Removing Toxic Metals from Water and Soil', Angewandte Chemie-International Edition, vol. 55, no. 5, pp. 1714-1718. https://doi.org/10.1002/anie.201508708

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T1 - Sulfur-Limonene Polysulfide: A Material Synthesized Entirely from Industrial By-Products and Its Use in Removing Toxic Metals from Water and Soil

AU - Crockett, Michael

AU - Evans, Austin

AU - Worthington, Max

AU - Albuquerque, Ines

AU - Slattery, Ashley

AU - Gibson, Christopher

AU - Campbell, Jonathan

AU - Lewis, David

AU - Bernardes, Goncalo

AU - Chalker, Justin

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AB - A polysulfide material was synthesized by the direct reaction of sulfur and d-limonene, by-products of the petroleum and citrus industries, respectively. The resulting material was processed into functional coatings or molded into solid devices for the removal of palladium and mercury salts from water and soil. The binding of mercury(II) to the sulfur-limonene polysulfide resulted in a color change. These properties motivate application in next-generation environmental remediation and mercury sensing.

KW - limonene

KW - polysulfide

KW - sulfur

KW - sustainable materials

KW - waste valorization

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Sulfur-Limonene Polysulfide: A Material Synthesized Entirely from Industrial By-Products and Its Use in Removing Toxic Metals from Water and Soil

Abstract

Keywords

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