13C CP/MAS NMR Spectroscopy of Magnesium-Anthracene and -Cyclooctatetraene Complexes: Graphite-Assisted Degradation of a Magnesium-Anthracene

William M. Brooks; Colin L. Raston; Rodney E. Sue; Frank J. Lincoln; Justin J. McGinnity

doi:10.1021/om00053a007

¹³C CP/MAS NMR Spectroscopy of Magnesium-Anthracene and -Cyclooctatetraene Complexes: Graphite-Assisted Degradation of a Magnesium-Anthracene

William M. Brooks
, Colin L. Raston
, Rodney E. Sue
, Frank J. Lincoln
, Justin J. McGinnity

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

¹³C CP/MAS NMR spectroscopy shows that [Mg(anthraceneXTHF)₂], derived from decomposition of [Mg(anthraceneKTHF)₃], has Mg-C9,10 interactions and that Mg(cyclooctatetraeneXTHF)_2.5 has an aromatic dianion: graphite accelerates the decomposition of [Mg(anthraceneXTHF)₃], in toluene (via[Mg(anthraceneX^THF)₂]) or diethyl ether, to its constituents, affording highly activated and finely divided magnesium (ca. 6 /μm) rather than an intercalation compound.

Original language	English
Pages (from-to)	2098-2100
Number of pages	3
Journal	Organometallics
Volume	10
Issue number	7
DOIs	https://doi.org/10.1021/om00053a007
Publication status	Published - 1 Jul 1991
Externally published	Yes

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title = "13C CP/MAS NMR Spectroscopy of Magnesium-Anthracene and -Cyclooctatetraene Complexes: Graphite-Assisted Degradation of a Magnesium-Anthracene",

abstract = "13C CP/MAS NMR spectroscopy shows that [Mg(anthraceneXTHF)2], derived from decomposition of [Mg(anthraceneKTHF)3], has Mg-C9,10 interactions and that Mg(cyclooctatetraeneXTHF)2.5 has an aromatic dianion: graphite accelerates the decomposition of [Mg(anthraceneXTHF)3], in toluene (via[Mg(anthraceneXTHF)2]) or diethyl ether, to its constituents, affording highly activated and finely divided magnesium (ca. 6 /μm) rather than an intercalation compound.",

author = "Brooks, \{William M.\} and Raston, \{Colin L.\} and Sue, \{Rodney E.\} and Lincoln, \{Frank J.\} and McGinnity, \{Justin J.\}",

year = "1991",

month = jul,

day = "1",

doi = "10.1021/om00053a007",

language = "English",

volume = "10",

pages = "2098--2100",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - 13C CP/MAS NMR Spectroscopy of Magnesium-Anthracene and -Cyclooctatetraene Complexes

T2 - Graphite-Assisted Degradation of a Magnesium-Anthracene

AU - Brooks, William M.

AU - Raston, Colin L.

AU - Sue, Rodney E.

AU - Lincoln, Frank J.

AU - McGinnity, Justin J.

PY - 1991/7/1

Y1 - 1991/7/1

N2 - 13C CP/MAS NMR spectroscopy shows that [Mg(anthraceneXTHF)2], derived from decomposition of [Mg(anthraceneKTHF)3], has Mg-C9,10 interactions and that Mg(cyclooctatetraeneXTHF)2.5 has an aromatic dianion: graphite accelerates the decomposition of [Mg(anthraceneXTHF)3], in toluene (via[Mg(anthraceneXTHF)2]) or diethyl ether, to its constituents, affording highly activated and finely divided magnesium (ca. 6 /μm) rather than an intercalation compound.

AB - 13C CP/MAS NMR spectroscopy shows that [Mg(anthraceneXTHF)2], derived from decomposition of [Mg(anthraceneKTHF)3], has Mg-C9,10 interactions and that Mg(cyclooctatetraeneXTHF)2.5 has an aromatic dianion: graphite accelerates the decomposition of [Mg(anthraceneXTHF)3], in toluene (via[Mg(anthraceneXTHF)2]) or diethyl ether, to its constituents, affording highly activated and finely divided magnesium (ca. 6 /μm) rather than an intercalation compound.

UR - https://www.scopus.com/pages/publications/0010955314

U2 - 10.1021/om00053a007

DO - 10.1021/om00053a007

M3 - Article

AN - SCOPUS:0010955314

SN - 0276-7333

VL - 10

SP - 2098

EP - 2100

JO - Organometallics

JF - Organometallics

IS - 7

ER -

¹³C CP/MAS NMR Spectroscopy of Magnesium-Anthracene and -Cyclooctatetraene Complexes: Graphite-Assisted Degradation of a Magnesium-Anthracene

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