Supramolecular assemblies of 1,2-dicarbadodecaborane(12) with bowl- shaped calix[5]arene

Michaele J. Hardie; Colin L. Raston

doi:10.1002/(SICI)1099-0682(199901)1999:1<195::AID-EJIC195>3.0.CO;2-D

Supramolecular assemblies of 1,2-dicarbadodecaborane(12) with bowl- shaped calix[5]arene

Michaele J. Hardie, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Treatment of globular 1,2-dicarbadodecaborane(12) (o-carborane) 1 with the bowl-shaped container molecule calix[5]arene 2 affords either the crystalline 1:1 or 1:2 host-guest complexes (o- carborane)(calix[5]arene)(CH₂Cl₂) 3, (o-carborane)(calix[5]arene)(toluene) 4 and (o-carborane)(calix[5]arene)₂(CH₂Cl₂)_0.5. The three complexes show a remarkable range of different supramolecular interplay beyond the common structural unit, a ball-and-socket nano-structure or supermolecule [(o-carborane) intersection set (calix[5]arene)]. Complex 3 forms dimeric [(o-carborane) intersection set (calix[5]arene)]₂ units, and 5 has an additional edge on interaction between the supermolecule and a secondary calix[5]arene host.

Original language	English
Pages (from-to)	195-200
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	1
DOIs	https://doi.org/10.1002/(SICI)1099-0682(199901)1999:1<195::AID-EJIC195>3.0.CO;2-D
Publication status	Published - 1 Jan 1999
Externally published	Yes

Keywords

Calixarene
Carboranes
Host-guest chemistry
Non-classical hydrogen bonding
Supramolecular chemistry

Access to Document

10.1002/(SICI)1099-0682(199901)1999:1<195::AID-EJIC195>3.0.CO;2-DLicence: In Copyright

Cite this

@article{9b18846fb6c7451cb9d75ae36db765f7,

title = "Supramolecular assemblies of 1,2-dicarbadodecaborane(12) with bowl- shaped calix[5]arene",

abstract = "Treatment of globular 1,2-dicarbadodecaborane(12) (o-carborane) 1 with the bowl-shaped container molecule calix[5]arene 2 affords either the crystalline 1:1 or 1:2 host-guest complexes (o- carborane)(calix[5]arene)(CH2Cl2) 3, (o-carborane)(calix[5]arene)(toluene) 4 and (o-carborane)(calix[5]arene)2(CH2Cl2)0.5. The three complexes show a remarkable range of different supramolecular interplay beyond the common structural unit, a ball-and-socket nano-structure or supermolecule [(o-carborane) intersection set (calix[5]arene)]. Complex 3 forms dimeric [(o-carborane) intersection set (calix[5]arene)]2 units, and 5 has an additional edge on interaction between the supermolecule and a secondary calix[5]arene host.",

keywords = "Calixarene, Carboranes, Host-guest chemistry, Non-classical hydrogen bonding, Supramolecular chemistry",

author = "Hardie, {Michaele J.} and Raston, {Colin L.}",

year = "1999",

month = jan,

day = "1",

doi = "10.1002/(SICI)1099-0682(199901)1999:1<195::AID-EJIC195>3.0.CO;2-D",

language = "English",

pages = "195--200",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

number = "1",

}

TY - JOUR

T1 - Supramolecular assemblies of 1,2-dicarbadodecaborane(12) with bowl- shaped calix[5]arene

AU - Hardie, Michaele J.

AU - Raston, Colin L.

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Treatment of globular 1,2-dicarbadodecaborane(12) (o-carborane) 1 with the bowl-shaped container molecule calix[5]arene 2 affords either the crystalline 1:1 or 1:2 host-guest complexes (o- carborane)(calix[5]arene)(CH2Cl2) 3, (o-carborane)(calix[5]arene)(toluene) 4 and (o-carborane)(calix[5]arene)2(CH2Cl2)0.5. The three complexes show a remarkable range of different supramolecular interplay beyond the common structural unit, a ball-and-socket nano-structure or supermolecule [(o-carborane) intersection set (calix[5]arene)]. Complex 3 forms dimeric [(o-carborane) intersection set (calix[5]arene)]2 units, and 5 has an additional edge on interaction between the supermolecule and a secondary calix[5]arene host.

AB - Treatment of globular 1,2-dicarbadodecaborane(12) (o-carborane) 1 with the bowl-shaped container molecule calix[5]arene 2 affords either the crystalline 1:1 or 1:2 host-guest complexes (o- carborane)(calix[5]arene)(CH2Cl2) 3, (o-carborane)(calix[5]arene)(toluene) 4 and (o-carborane)(calix[5]arene)2(CH2Cl2)0.5. The three complexes show a remarkable range of different supramolecular interplay beyond the common structural unit, a ball-and-socket nano-structure or supermolecule [(o-carborane) intersection set (calix[5]arene)]. Complex 3 forms dimeric [(o-carborane) intersection set (calix[5]arene)]2 units, and 5 has an additional edge on interaction between the supermolecule and a secondary calix[5]arene host.

KW - Calixarene

KW - Carboranes

KW - Host-guest chemistry

KW - Non-classical hydrogen bonding

KW - Supramolecular chemistry

UR - http://www.scopus.com/inward/record.url?scp=0032799207&partnerID=8YFLogxK

U2 - 10.1002/(SICI)1099-0682(199901)1999:1<195::AID-EJIC195>3.0.CO;2-D

DO - 10.1002/(SICI)1099-0682(199901)1999:1<195::AID-EJIC195>3.0.CO;2-D

M3 - Article

AN - SCOPUS:0032799207

SP - 195

EP - 200

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 1

ER -

Supramolecular assemblies of 1,2-dicarbadodecaborane(12) with bowl- shaped calix[5]arene

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this