Supramolecular assemblies of globular main group cage species

Philip C. Andrews; Michaele J. Hardie; Colin L. Raston

doi:10.1016/S0010-8545(99)00134-4

Supramolecular assemblies of globular main group cage species

Philip C. Andrews, Michaele J. Hardie, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

A comprehensive survey of the supramolecular chemistry of main group cage species covers their host-guest chemistry, molecular recognition, and inclusion/intercalation compounds. A major part of the review deals with carboranes, o-, m-, p-B₂C₁₀H₁₂, which show a remarkable ability to self assemble via hydrogen bonds involving the C-H groups, bifurcated hydrogen bonds (C-H⋯(O)₂) and C-H⋯π interactions. Group 15/16 cage molecules form host-guest supermolecules and extended structures with rigid saddle shape metal macrocycles. Insight into future prospects in this field is presented.

Original language	English
Pages (from-to)	169-198
Number of pages	30
Journal	Coordination Chemistry Reviews
Volume	189
Issue number	1
DOIs	https://doi.org/10.1016/S0010-8545(99)00134-4
Publication status	Published - 1 Jan 1999
Externally published	Yes

Keywords

Host-guest chemistry
Hydrogen bonds
Inclusion compounds
Intercalation compounds
Metal macrocycles
Supramolecules

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AU - Raston, Colin L.

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AB - A comprehensive survey of the supramolecular chemistry of main group cage species covers their host-guest chemistry, molecular recognition, and inclusion/intercalation compounds. A major part of the review deals with carboranes, o-, m-, p-B2C10H12, which show a remarkable ability to self assemble via hydrogen bonds involving the C-H groups, bifurcated hydrogen bonds (C-H⋯(O)2) and C-H⋯π interactions. Group 15/16 cage molecules form host-guest supermolecules and extended structures with rigid saddle shape metal macrocycles. Insight into future prospects in this field is presented.

KW - Host-guest chemistry

KW - Hydrogen bonds

KW - Inclusion compounds

KW - Intercalation compounds

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Supramolecular assemblies of globular main group cage species

Abstract

Keywords

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