Supramolecular chemistry of anionic cobalt(III) bis(dicarbollide) and cyclotriveratrylene in the solid state and the gas phase

Michaele J. Hardie, Colin L. Raston

Research output: Contribution to journalArticlepeer-review

57 Citations (Scopus)

Abstract

Polymer layers templated around [Co(C2B9H11)2]- (1) counter ions are one of the structural features of the two-dimensional coordination polymer obtained in crystalline form from Na-1 and cyclotriveratrylene (CTV). In solution the [Na(CTV)]1(CF3CH2OH)0.25 coordination polymer breaks up and [Na(n)(CTV(m)](n+) clusters are present in the gas phase and can complex one or two [Co(C2B9H11)1 ions.

Original languageEnglish
Pages (from-to)3835-3839
Number of pages5
JournalAngewandte Chemie - International Edition
Volume39
Issue number21
DOIs
Publication statusPublished - 3 Nov 2000
Externally publishedYes

Keywords

  • Carboranes
  • Cobalt
  • Cyclotriveratrylene
  • Host-guest chemistry
  • Supramolecular chemistry

Fingerprint

Dive into the research topics of 'Supramolecular chemistry of anionic cobalt(III) bis(dicarbollide) and cyclotriveratrylene in the solid state and the gas phase'. Together they form a unique fingerprint.

Cite this