Supramolecular chemistry of anionic cobalt(III) bis(dicarbollide) and cyclotriveratrylene in the solid state and the gas phase

Michaele J. Hardie; Colin L. Raston

doi:10.1002/1521-3773(20001103)39:21<3835::AID-ANIE3835>3.0.CO;2-Q

Supramolecular chemistry of anionic cobalt(III) bis(dicarbollide) and cyclotriveratrylene in the solid state and the gas phase

Michaele J. Hardie, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

Polymer layers templated around [Co(C₂B₉H₁₁)₂]^- (1) counter ions are one of the structural features of the two-dimensional coordination polymer obtained in crystalline form from Na-1 and cyclotriveratrylene (CTV). In solution the [Na(CTV)]1(CF₃CH₂OH)_0.25 coordination polymer breaks up and [Na(n)(CTV(m)](n+) clusters are present in the gas phase and can complex one or two [Co(C₂B₉H₁₁)¹ ions.

Original language	English
Pages (from-to)	3835-3839
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	21
DOIs	https://doi.org/10.1002/1521-3773(20001103)39:21<3835::AID-ANIE3835>3.0.CO;2-Q
Publication status	Published - 3 Nov 2000
Externally published	Yes

Keywords

Carboranes
Cobalt
Cyclotriveratrylene
Host-guest chemistry
Supramolecular chemistry

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10.1002/1521-3773(20001103)39:21<3835::AID-ANIE3835>3.0.CO;2-QLicence: In Copyright

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title = "Supramolecular chemistry of anionic cobalt(III) bis(dicarbollide) and cyclotriveratrylene in the solid state and the gas phase",

abstract = "Polymer layers templated around [Co(C2B9H11)2]- (1) counter ions are one of the structural features of the two-dimensional coordination polymer obtained in crystalline form from Na-1 and cyclotriveratrylene (CTV). In solution the [Na(CTV)]1(CF3CH2OH)0.25 coordination polymer breaks up and [Na(n)(CTV(m)](n+) clusters are present in the gas phase and can complex one or two [Co(C2B9H11)1 ions.",

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AU - Hardie, Michaele J.

AU - Raston, Colin L.

PY - 2000/11/3

Y1 - 2000/11/3

N2 - Polymer layers templated around [Co(C2B9H11)2]- (1) counter ions are one of the structural features of the two-dimensional coordination polymer obtained in crystalline form from Na-1 and cyclotriveratrylene (CTV). In solution the [Na(CTV)]1(CF3CH2OH)0.25 coordination polymer breaks up and [Na(n)(CTV(m)](n+) clusters are present in the gas phase and can complex one or two [Co(C2B9H11)1 ions.

AB - Polymer layers templated around [Co(C2B9H11)2]- (1) counter ions are one of the structural features of the two-dimensional coordination polymer obtained in crystalline form from Na-1 and cyclotriveratrylene (CTV). In solution the [Na(CTV)]1(CF3CH2OH)0.25 coordination polymer breaks up and [Na(n)(CTV(m)](n+) clusters are present in the gas phase and can complex one or two [Co(C2B9H11)1 ions.

KW - Carboranes

KW - Cobalt

KW - Cyclotriveratrylene

KW - Host-guest chemistry

KW - Supramolecular chemistry

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DO - 10.1002/1521-3773(20001103)39:21<3835::AID-ANIE3835>3.0.CO;2-Q

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Supramolecular chemistry of anionic cobalt(III) bis(dicarbollide) and cyclotriveratrylene in the solid state and the gas phase

Abstract

Keywords

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