TY - JOUR
T1 - Sustainable supercapacitor electrode material contains green synthesized expired drug-functionalized graphene oxide, meat waste-derived carbon, and ionic liquid
T2 - Electrochemical performance and management strategies
AU - Seyedhosseini, Zahra
AU - Najafi, Mohammad Dashti
AU - Aliakbari, Raouf
AU - Kowsari, Elaheh
AU - Naderi, Hamid Reza
AU - Motamedisade, Anahita
AU - Adhikari, Sunita G.
AU - Gheibi, Mohammad
PY - 2025/4/1
Y1 - 2025/4/1
N2 - Reusing waste and seemingly worthless resources has attracted increasing attention. This work used meat waste (MW) to prepare activated carbon (AC) through pyrolysis. AC derived from MW was composited with expired Ganciclovir-functionalized graphene oxide (GG) and 1-benzyl-3-methyl-1H-imidazol-3-ium bromide ionic liquid (IL) to introduce a sustainable composite (GG-MW-IL) for energy storage. Functionalized graphene oxide was prepared in a green solvent (IL) to minimize the environmental impact. A series of instrumental tests confirmed the successful synthesis. The most important data during the structural characterization was the specific surface area of 288.11 m2 g−1 for GG-MW-IL composite, which made it suitable for energy storage applications. In the three-electrode (3E) system, the composite electrode recorded a specific capacity of 459 F g−1 @ 1 A g−1. It showed retention of 97.2 % (10,000 charge/discharge loops), demonstrated low resistance, and facilitated effective charge transfer in the 3E system. When configured in a symmetric two-electrode (2E) system (GG-MW-IL//GG-MW-IL), it displayed a specific capacity of 228 F g−1 @ 0.5 A g−1. After 10,000 charge/discharge loops, it maintained a retention capacity of 94.2 % and achieved high energy and power density. Considering the excellent behavior of GG-MW-IL electrodes in a natural supercapacitor system, using low-risk, green, and recycled materials shows the potential to replace traditional materials. The assessment of designed supercapacitors within the circular economy framework highlights that GG-MW-IL exhibits favorable executive-economical attributes, making it particularly suitable for adoption within the energy industry compared to other options.
AB - Reusing waste and seemingly worthless resources has attracted increasing attention. This work used meat waste (MW) to prepare activated carbon (AC) through pyrolysis. AC derived from MW was composited with expired Ganciclovir-functionalized graphene oxide (GG) and 1-benzyl-3-methyl-1H-imidazol-3-ium bromide ionic liquid (IL) to introduce a sustainable composite (GG-MW-IL) for energy storage. Functionalized graphene oxide was prepared in a green solvent (IL) to minimize the environmental impact. A series of instrumental tests confirmed the successful synthesis. The most important data during the structural characterization was the specific surface area of 288.11 m2 g−1 for GG-MW-IL composite, which made it suitable for energy storage applications. In the three-electrode (3E) system, the composite electrode recorded a specific capacity of 459 F g−1 @ 1 A g−1. It showed retention of 97.2 % (10,000 charge/discharge loops), demonstrated low resistance, and facilitated effective charge transfer in the 3E system. When configured in a symmetric two-electrode (2E) system (GG-MW-IL//GG-MW-IL), it displayed a specific capacity of 228 F g−1 @ 0.5 A g−1. After 10,000 charge/discharge loops, it maintained a retention capacity of 94.2 % and achieved high energy and power density. Considering the excellent behavior of GG-MW-IL electrodes in a natural supercapacitor system, using low-risk, green, and recycled materials shows the potential to replace traditional materials. The assessment of designed supercapacitors within the circular economy framework highlights that GG-MW-IL exhibits favorable executive-economical attributes, making it particularly suitable for adoption within the energy industry compared to other options.
KW - Circular economy
KW - Expired drug
KW - Ganciclovir-functionalized graphene oxide
KW - Meat waste
KW - Sustainable supercapacitor
UR - http://www.scopus.com/inward/record.url?scp=85217222337&partnerID=8YFLogxK
U2 - 10.1016/j.est.2025.115742
DO - 10.1016/j.est.2025.115742
M3 - Article
AN - SCOPUS:85217222337
SN - 2352-152X
VL - 114
JO - Journal of Energy Storage
JF - Journal of Energy Storage
IS - Part A
M1 - 115742
ER -