Synchrotron FTIR Microscopy of Langmuir-Blodgett Monolayers and Polyelectrolyte Multilayers at the Solid-Solid Interface

David Beattie; Audrey Beaussart; A. Mierczynska-Vasilev; Sarah Harmer; Benjamin Thierry; Liljana Puskar; Mark Tobin

doi:10.1021/la2045543

Synchrotron FTIR Microscopy of Langmuir-Blodgett Monolayers and Polyelectrolyte Multilayers at the Solid-Solid Interface

David Beattie, Audrey Beaussart, A. Mierczynska-Vasilev, Sarah Harmer, Benjamin Thierry, Liljana Puskar, Mark Tobin

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Synchrotron FTIR microscopy has been used to probe the structure of model boundary lubricant layers confined at the solid-solid interface. The combination of high brightness of the IR source and a novel contact geometry that uses a hemispherical internal reflection element as the means for light delivery has enabled the detection of <2.5 nm thin monolayer lubricant layers in the solid-solid contact, in addition to allowing for spectral acquisition from specific regions of the contact. Spectra of hydration water from within a confined polyelectrolyte multilayer film have also been acquired, highlighting the altered hydrogen bonding environment within the polymer layer.

Original language	English
Pages (from-to)	1683-1688
Number of pages	6
Journal	Langmuir
Volume	28
Issue number	3
DOIs	https://doi.org/10.1021/la2045543
Publication status	Published - 24 Jan 2012

Access to Document

10.1021/la2045543

Fingerprint Dive into the research topics of 'Synchrotron FTIR Microscopy of Langmuir-Blodgett Monolayers and Polyelectrolyte Multilayers at the Solid-Solid Interface'. Together they form a unique fingerprint.

Cite this

@article{19ff1967ce8a4b48a8307cdf195c7844,

title = "Synchrotron FTIR Microscopy of Langmuir-Blodgett Monolayers and Polyelectrolyte Multilayers at the Solid-Solid Interface",

abstract = "Synchrotron FTIR microscopy has been used to probe the structure of model boundary lubricant layers confined at the solid-solid interface. The combination of high brightness of the IR source and a novel contact geometry that uses a hemispherical internal reflection element as the means for light delivery has enabled the detection of <2.5 nm thin monolayer lubricant layers in the solid-solid contact, in addition to allowing for spectral acquisition from specific regions of the contact. Spectra of hydration water from within a confined polyelectrolyte multilayer film have also been acquired, highlighting the altered hydrogen bonding environment within the polymer layer.",

author = "David Beattie and Audrey Beaussart and A. Mierczynska-Vasilev and Sarah Harmer and Benjamin Thierry and Liljana Puskar and Mark Tobin",

year = "2012",

month = jan,

day = "24",

doi = "10.1021/la2045543",

language = "English",

volume = "28",

pages = "1683--1688",

journal = "Langmuir",

issn = "0743-7463",

publisher = "American Chemical Society",

number = "3",

}

Synchrotron FTIR Microscopy of Langmuir-Blodgett Monolayers and Polyelectrolyte Multilayers at the Solid-Solid Interface. / Beattie, David; Beaussart, Audrey; Mierczynska-Vasilev, A.; Harmer, Sarah; Thierry, Benjamin; Puskar, Liljana; Tobin, Mark.

In: Langmuir, Vol. 28, No. 3, 24.01.2012, p. 1683-1688.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synchrotron FTIR Microscopy of Langmuir-Blodgett Monolayers and Polyelectrolyte Multilayers at the Solid-Solid Interface

AU - Beattie, David

AU - Beaussart, Audrey

AU - Mierczynska-Vasilev, A.

AU - Harmer, Sarah

AU - Thierry, Benjamin

AU - Puskar, Liljana

AU - Tobin, Mark

PY - 2012/1/24

Y1 - 2012/1/24

N2 - Synchrotron FTIR microscopy has been used to probe the structure of model boundary lubricant layers confined at the solid-solid interface. The combination of high brightness of the IR source and a novel contact geometry that uses a hemispherical internal reflection element as the means for light delivery has enabled the detection of <2.5 nm thin monolayer lubricant layers in the solid-solid contact, in addition to allowing for spectral acquisition from specific regions of the contact. Spectra of hydration water from within a confined polyelectrolyte multilayer film have also been acquired, highlighting the altered hydrogen bonding environment within the polymer layer.

AB - Synchrotron FTIR microscopy has been used to probe the structure of model boundary lubricant layers confined at the solid-solid interface. The combination of high brightness of the IR source and a novel contact geometry that uses a hemispherical internal reflection element as the means for light delivery has enabled the detection of <2.5 nm thin monolayer lubricant layers in the solid-solid contact, in addition to allowing for spectral acquisition from specific regions of the contact. Spectra of hydration water from within a confined polyelectrolyte multilayer film have also been acquired, highlighting the altered hydrogen bonding environment within the polymer layer.

UR - http://www.scopus.com/inward/record.url?scp=84856169735&partnerID=8YFLogxK

U2 - 10.1021/la2045543

DO - 10.1021/la2045543

M3 - Article

VL - 28

SP - 1683

EP - 1688

JO - Langmuir

JF - Langmuir

SN - 0743-7463

IS - 3

ER -

Synchrotron FTIR Microscopy of Langmuir-Blodgett Monolayers and Polyelectrolyte Multilayers at the Solid-Solid Interface

Abstract

Access to Document

Other files and links

Cite this