TY - JOUR
T1 - Synthesis and crystal structure of the silver(I) alkyl species, [{2-(Me3Si)2C(Ag)C5H4N} 2], a dimeric compound void of electron-deficient bonding
AU - Papasergio, Rocco I.
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1984/5/1
Y1 - 1984/5/1
N2 - The silver(I) alkyl complex [{2-(Me3Si)2C(Ag)C 5H4N}2], prepared by the reaction of the analogous lithium alkyl with AgBF4 in tetrahydrofuran, is a binuclear complex in which the metal ion is not involved in electron-deficient bonding, being bound by a carbon atom at 2.154(5) Å and a nitrogen atom of a centrosymmetrically related ligand at 2.160(5) Å; the Ag⋯Ag′ separation is 2.654(1) Å.
AB - The silver(I) alkyl complex [{2-(Me3Si)2C(Ag)C 5H4N}2], prepared by the reaction of the analogous lithium alkyl with AgBF4 in tetrahydrofuran, is a binuclear complex in which the metal ion is not involved in electron-deficient bonding, being bound by a carbon atom at 2.154(5) Å and a nitrogen atom of a centrosymmetrically related ligand at 2.160(5) Å; the Ag⋯Ag′ separation is 2.654(1) Å.
UR - http://www.scopus.com/inward/record.url?scp=37049113382&partnerID=8YFLogxK
U2 - 10.1039/c39840000612
DO - 10.1039/c39840000612
M3 - Article
AN - SCOPUS:37049113382
SN - 0022-4936
SP - 612
EP - 613
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 9
ER -