Synthesis and crystal structure of the silver(I) alkyl species, [{2-(Me3Si)2C(Ag)C5H4N} 2], a dimeric compound void of electron-deficient bonding

Rocco I. Papasergio; Colin L. Raston; Allan H. White

doi:10.1039/c39840000612

Synthesis and crystal structure of the silver(I) alkyl species, [{2-(Me₃Si)₂C(Ag)C₅H₄N} ₂], a dimeric compound void of electron-deficient bonding

Rocco I. Papasergio
, Colin L. Raston
, Allan H. White

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

The silver(I) alkyl complex [{2-(Me₃Si)₂C(Ag)C ₅H₄N}₂], prepared by the reaction of the analogous lithium alkyl with AgBF₄ in tetrahydrofuran, is a binuclear complex in which the metal ion is not involved in electron-deficient bonding, being bound by a carbon atom at 2.154(5) Å and a nitrogen atom of a centrosymmetrically related ligand at 2.160(5) Å; the Ag⋯Ag′ separation is 2.654(1) Å.

Original language	English
Pages (from-to)	612-613
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/c39840000612
Publication status	Published - 1 May 1984
Externally published	Yes

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title = "Synthesis and crystal structure of the silver(I) alkyl species, [\{2-(Me3Si)2C(Ag)C5H4N\} 2], a dimeric compound void of electron-deficient bonding",

abstract = "The silver(I) alkyl complex [\{2-(Me3Si)2C(Ag)C 5H4N\}2], prepared by the reaction of the analogous lithium alkyl with AgBF4 in tetrahydrofuran, is a binuclear complex in which the metal ion is not involved in electron-deficient bonding, being bound by a carbon atom at 2.154(5) {\AA} and a nitrogen atom of a centrosymmetrically related ligand at 2.160(5) {\AA}; the Ag⋯Ag′ separation is 2.654(1) {\AA}.",

author = "Papasergio, \{Rocco I.\} and Raston, \{Colin L.\} and White, \{Allan H.\}",

year = "1984",

month = may,

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doi = "10.1039/c39840000612",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T1 - Synthesis and crystal structure of the silver(I) alkyl species, [{2-(Me3Si)2C(Ag)C5H4N} 2], a dimeric compound void of electron-deficient bonding

AU - Papasergio, Rocco I.

AU - Raston, Colin L.

AU - White, Allan H.

PY - 1984/5/1

Y1 - 1984/5/1

N2 - The silver(I) alkyl complex [{2-(Me3Si)2C(Ag)C 5H4N}2], prepared by the reaction of the analogous lithium alkyl with AgBF4 in tetrahydrofuran, is a binuclear complex in which the metal ion is not involved in electron-deficient bonding, being bound by a carbon atom at 2.154(5) Å and a nitrogen atom of a centrosymmetrically related ligand at 2.160(5) Å; the Ag⋯Ag′ separation is 2.654(1) Å.

AB - The silver(I) alkyl complex [{2-(Me3Si)2C(Ag)C 5H4N}2], prepared by the reaction of the analogous lithium alkyl with AgBF4 in tetrahydrofuran, is a binuclear complex in which the metal ion is not involved in electron-deficient bonding, being bound by a carbon atom at 2.154(5) Å and a nitrogen atom of a centrosymmetrically related ligand at 2.160(5) Å; the Ag⋯Ag′ separation is 2.654(1) Å.

UR - https://www.scopus.com/pages/publications/37049113382

U2 - 10.1039/c39840000612

DO - 10.1039/c39840000612

M3 - Article

AN - SCOPUS:37049113382

SN - 0022-4936

SP - 612

EP - 613

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 9

ER -

Synthesis and crystal structure of the silver(I) alkyl species, [{2-(Me₃Si)₂C(Ag)C₅H₄N} ₂], a dimeric compound void of electron-deficient bonding

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