Synthesis and modelling of novel rigid rods derived from a simple pentacyclic bis-norbornene [1]

Davor Margetic; Martin R. Johnston; Edward R.T. Tiekink; Ronald N. Warrener

doi:10.1016/S0040-4039(98)00999-X

Synthesis and modelling of novel rigid rods derived from a simple pentacyclic bis-norbornene [1]

Davor Margetic, Martin R. Johnston, Edward R.T. Tiekink, Ronald N. Warrener

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

New rigid rods with 4σ, 6σ, 10σ, 12σ, and 16σ bond separations have been prepared from the pentacyclic diene 3 using ACE (alkene plus cyclobutene epoxide) and s-tetrazine coupling techniques and their shapes evaluated using AM1 calculations. The X-ray structure of the 6σ-rod 5 is reported.

Original language	English
Pages (from-to)	5277-5280
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	29
DOIs	https://doi.org/10.1016/S0040-4039(98)00999-X
Publication status	Published - 16 Jul 1998
Externally published	Yes

Keywords

Cycloaddition
Molecular modelling
Stereoselection
Tetrazines

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10.1016/S0040-4039(98)00999-XLicence: In Copyright

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AU - Warrener, Ronald N.

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AB - New rigid rods with 4σ, 6σ, 10σ, 12σ, and 16σ bond separations have been prepared from the pentacyclic diene 3 using ACE (alkene plus cyclobutene epoxide) and s-tetrazine coupling techniques and their shapes evaluated using AM1 calculations. The X-ray structure of the 6σ-rod 5 is reported.

KW - Cycloaddition

KW - Molecular modelling

KW - Stereoselection

KW - Tetrazines

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JF - Tetrahedron Letters

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ER -

Synthesis and modelling of novel rigid rods derived from a simple pentacyclic bis-norbornene [1]

Abstract

Keywords

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