Synthesis and modelling of novel rigid rods derived from a simple pentacyclic bis-norbornene [1]

Davor Margetic; Martin R. Johnston; Edward R.T. Tiekink; Ronald N. Warrener

doi:10.1016/S0040-4039(98)00999-X

Synthesis and modelling of novel rigid rods derived from a simple pentacyclic bis-norbornene [1]

Davor Margetic, Martin R. Johnston, Edward R.T. Tiekink, Ronald N. Warrener

Research output: Contribution to journal › Article

29 Citations (Scopus)

Abstract

New rigid rods with 4σ, 6σ, 10σ, 12σ, and 16σ bond separations have been prepared from the pentacyclic diene 3 using ACE (alkene plus cyclobutene epoxide) and s-tetrazine coupling techniques and their shapes evaluated using AM1 calculations. The X-ray structure of the 6σ-rod 5 is reported.

Original language	English
Pages (from-to)	5277-5280
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	29
DOIs	https://doi.org/10.1016/S0040-4039(98)00999-X
Publication status	Published - 16 Jul 1998
Externally published	Yes

Keywords

Cycloaddition
Molecular modelling
Stereoselection
Tetrazines

Access to Document

10.1016/S0040-4039(98)00999-XLicence: In Copyright

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Margetic, D., Johnston, M. R., Tiekink, E. R. T., & Warrener, R. N. (1998). Synthesis and modelling of novel rigid rods derived from a simple pentacyclic bis-norbornene [1]. Tetrahedron Letters, 39(29), 5277-5280. https://doi.org/10.1016/S0040-4039(98)00999-X

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