Synthesis and trans-β-carotenoid inclusion properties of a new class of water soluble calixarenes

Mohamed Makha; Ian R. McKinnon; Colin L. Raston

doi:10.1039/B207850C

Synthesis and trans-β-carotenoid inclusion properties of a new class of water soluble calixarenes

Mohamed Makha, Ian R. McKinnon, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

The paper describes the synthesis of water soluble sulfonated calixarenes derived from p-benzylcalix[5,6,7,8]arenes and p-cumylcalix[4,6]arene along with their chlorosulfonyl derivatives. Inclusion phenomena of the sulfonated p-benzyl and p-phenyl calix[5,6]arenes towards carotenoids are also reported; ¹H NMR, UV-VIS and light scattering experiments are consistent with a model in which the carotenoid is surrounded by two calixarenes and these supermolecules form large aggregates, 100-150 nm in diameter.

Original language	English
Pages (from-to)	1801-1806
Number of pages	6
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	11
DOIs	https://doi.org/10.1039/B207850C
Publication status	Published - 28 Nov 2002
Externally published	Yes

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AU - McKinnon, Ian R.

AU - Raston, Colin L.

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AB - The paper describes the synthesis of water soluble sulfonated calixarenes derived from p-benzylcalix[5,6,7,8]arenes and p-cumylcalix[4,6]arene along with their chlorosulfonyl derivatives. Inclusion phenomena of the sulfonated p-benzyl and p-phenyl calix[5,6]arenes towards carotenoids are also reported; 1H NMR, UV-VIS and light scattering experiments are consistent with a model in which the carotenoid is surrounded by two calixarenes and these supermolecules form large aggregates, 100-150 nm in diameter.

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Synthesis and trans-β-carotenoid inclusion properties of a new class of water soluble calixarenes

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