TY - JOUR
T1 - Synthesis of 5,7-dihydrodibenzo[c,e]metallepins via a new di-grignard or dilithium reagent
AU - Leung, Wing Por
AU - Raston, Colin L.
PY - 1982/12/7
Y1 - 1982/12/7
N2 - Thermally robust metallacycles [M(η-C5H5)2L] ( L [(2-CH2C6H4)2]2-, M Ti, Zr, Hf) and [SnPh2L] have been obtained from the newly developed reagents, L[MgCl(thf)n]2 and L[Li(tmeda)]2, as has the silylated derivative, [2-(Me3SiCH2)C6H4]2. A new radical anion of 9,10-dihydrophenanthrene derived from the reaction of lithium and LCl2 or LBr2 in thf has been detected.
AB - Thermally robust metallacycles [M(η-C5H5)2L] ( L [(2-CH2C6H4)2]2-, M Ti, Zr, Hf) and [SnPh2L] have been obtained from the newly developed reagents, L[MgCl(thf)n]2 and L[Li(tmeda)]2, as has the silylated derivative, [2-(Me3SiCH2)C6H4]2. A new radical anion of 9,10-dihydrophenanthrene derived from the reaction of lithium and LCl2 or LBr2 in thf has been detected.
UR - http://www.scopus.com/inward/record.url?scp=0009801581&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)93986-X
DO - 10.1016/S0022-328X(00)93986-X
M3 - Article
AN - SCOPUS:0009801581
SN - 0022-328X
VL - 240
SP - C1
JO - JOURNAL OF ORGANOMETALLIC CHEMISTRY
JF - JOURNAL OF ORGANOMETALLIC CHEMISTRY
IS - 1
ER -