Synthesis of 5,7-dihydrodibenzo[c,e]metallepins via a new di-grignard or dilithium reagent

Wing Por Leung, Colin L. Raston

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Thermally robust metallacycles [M(η-C5H5)2L] ( L [(2-CH2C6H4)2]2-, M Ti, Zr, Hf) and [SnPh2L] have been obtained from the newly developed reagents, L[MgCl(thf)n]2 and L[Li(tmeda)]2, as has the silylated derivative, [2-(Me3SiCH2)C6H4]2. A new radical anion of 9,10-dihydrophenanthrene derived from the reaction of lithium and LCl2 or LBr2 in thf has been detected.

Original languageEnglish
Pages (from-to)C1
JournalJOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume240
Issue number1
DOIs
Publication statusPublished - 7 Dec 1982
Externally publishedYes

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