Synthesis of Highly Enantio-Enriched Heliespirones A and C by a Diastereoselective Aromatic Claisen Rearrangement

Philip Norcott; Christopher S.P. McErlean

doi:10.1071/CH18019

Synthesis of Highly Enantio-Enriched Heliespirones A and C by a Diastereoselective Aromatic Claisen Rearrangement

Philip Norcott, Christopher S.P. McErlean

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Computational methods were used to investigate the stereochemical course of the extra-annular Claisen rearrangement. The stereochemical fidelity of the synthetic strategy and comparison of the optical properties support the hypothesis that the heliespirones are scalemic natural products.

Original language	English
Pages (from-to)	366-372
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	71
Issue number	5
DOIs	https://doi.org/10.1071/CH18019
Publication status	Published - 2018
Externally published	Yes

Keywords

Computational methods
Enantio-Enriched Heliespirones
Heliespirones
extra-annular Claisen rearrangement
Stereochemical analysis

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10.1071/CH18019Licence: In Copyright

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abstract = "Computational methods were used to investigate the stereochemical course of the extra-annular Claisen rearrangement. The stereochemical fidelity of the synthetic strategy and comparison of the optical properties support the hypothesis that the heliespirones are scalemic natural products.",

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doi = "10.1071/CH18019",

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AB - Computational methods were used to investigate the stereochemical course of the extra-annular Claisen rearrangement. The stereochemical fidelity of the synthetic strategy and comparison of the optical properties support the hypothesis that the heliespirones are scalemic natural products.

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KW - Enantio-Enriched Heliespirones

KW - Heliespirones

KW - extra-annular Claisen rearrangement

KW - Stereochemical analysis

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Synthesis of Highly Enantio-Enriched Heliespirones A and C by a Diastereoselective Aromatic Claisen Rearrangement

Abstract

Keywords

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